Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 13, Problem 13.49QP
What is osmosis? What is a semipermeable membrane?
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Predict the major products of this organic reaction:
H
OH
1. LiAlH4
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
G
C
टे
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
CI
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
G
टे
Chapter 13 Solutions
Chemistry: Atoms First
Ch. 13.2 - Determine for each solute whether the solubility...Ch. 13.2 - Predict whether iodine (I2) is more soluble in...Ch. 13.2 - Prob. 1PPBCh. 13.2 - Prob. 1PPCCh. 13.3 - Prob. 13.2WECh. 13.3 - Determine (a) the molality and (b) the percent by...Ch. 13.3 - Prob. 2PPBCh. 13.3 - Prob. 2PPCCh. 13.3 - Rubbing alcohol is a mixture of isopropyl alcohol...Ch. 13.3 - Prob. 3PPA
Ch. 13.3 - Prob. 3PPBCh. 13.3 - Prob. 3PPCCh. 13.3 - Prob. 13.3.1SRCh. 13.3 - Prob. 13.3.2SRCh. 13.3 - Prob. 13.3.3SRCh. 13.3 - At 25.0C, an aqueous solution that is 25.0 percent...Ch. 13.4 - Calculate the concentration of carbon dioxide in a...Ch. 13.4 - Calculate the concentration of CO2 in water at 25C...Ch. 13.4 - Prob. 4PPBCh. 13.4 - Prob. 4PPCCh. 13.4 - Prob. 13.4.1SRCh. 13.4 - Prob. 13.4.2SRCh. 13.5 - Prob. 13.5WECh. 13.5 - Calculate the vapor pressure of a solution made by...Ch. 13.5 - Calculate the mass of urea that should be...Ch. 13.5 - The diagrams [(i)(iv)] represent four closed...Ch. 13.5 - Ethylene glycol [CH2(OH)CH2(OH)] is a common...Ch. 13.5 - Prob. 6PPACh. 13.5 - What mass of ethylene glycol must be added to 1525...Ch. 13.5 - Prob. 6PPCCh. 13.5 - Prob. 13.7WECh. 13.5 - Prob. 7PPACh. 13.5 - Prob. 7PPBCh. 13.5 - A solution contains 75.0 g of glucose (molar mass...Ch. 13.5 - Prob. 13.5.2SRCh. 13.5 - Prob. 13.5.3SRCh. 13.5 - A 1.00-m solution of HC1 has a freezing point of...Ch. 13.6 - Quinine was the first drug widely used to treat...Ch. 13.6 - Prob. 8PPACh. 13.6 - Prob. 8PPBCh. 13.6 - Prob. 8PPCCh. 13.6 - Prob. 13.9WECh. 13.6 - A solution made by dissolving 25 mg of insulin in...Ch. 13.6 - What mass of insulin must be dissolved in 50.0 mL...Ch. 13.6 - The first diagram represents one aqueous solution...Ch. 13.6 - Prob. 13.10WECh. 13.6 - An aqueous solution that is 0.0100 M in acetic...Ch. 13.6 - Prob. 10PPBCh. 13.6 - Prob. 10PPCCh. 13.6 - Prob. 13.6.1SRCh. 13.6 - A 0.010-M solution of the weak electrolyte HA has...Ch. 13 - Which of the following processes is accompanied by...Ch. 13 - For each of the processes depicted here, determine...Ch. 13 - For each of the processes depicted here, determine...Ch. 13 - Prob. 13.4KSPCh. 13 - Prob. 13.1QPCh. 13 - Prob. 13.2QPCh. 13 - Prob. 13.3QPCh. 13 - Prob. 13.4QPCh. 13 - Prob. 13.5QPCh. 13 - Prob. 13.6QPCh. 13 - Explain why dissolving a solid almost always leads...Ch. 13 - Describe the factors that affect the solubility of...Ch. 13 - Prob. 13.9QPCh. 13 - Prob. 13.10QPCh. 13 - Arrange the following compounds in order of...Ch. 13 - Prob. 13.12QPCh. 13 - Prob. 13.13QPCh. 13 - Prob. 13.14QPCh. 13 - Prob. 13.15QPCh. 13 - Calculate the amount of water (in crams) that must...Ch. 13 - Calculate the molality of each of the following...Ch. 13 - Prob. 13.18QPCh. 13 - Calculate the molalities of the following aqueous...Ch. 13 - For dilute aqueous solutions in which the density...Ch. 13 - Prob. 13.21QPCh. 13 - PepsiCo, maker of Pepsi, announced in April 2015...Ch. 13 - After sales of new Diet Pepsi proved...Ch. 13 - The density of an aqueous solution containing 25.0...Ch. 13 - Prob. 13.25QPCh. 13 - Discuss the factors that influence the solubility...Ch. 13 - What is thermal pollution? Why is it harmful to...Ch. 13 - Prob. 13.28QPCh. 13 - A student is observing two beakers of water. One...Ch. 13 - A man bought a goldfish in a pet shop. Upon...Ch. 13 - The solubility of KNO3 is 155 g per 100 g of water...Ch. 13 - A 3.20-g sample of a salt dissolves in 9.10 g of...Ch. 13 - The solubility of CO2 in water at 25C and 1 atm is...Ch. 13 - Prob. 13.34QPCh. 13 - Fish breathe the dissolved air in water through...Ch. 13 - The solubility of N2 in blood at 37C and at a...Ch. 13 - The difference between water-soluble and...Ch. 13 - Predict whether each vitamin will be water soluble...Ch. 13 - Prob. 13.39QPCh. 13 - The first diagram represents an open system with...Ch. 13 - The diagrams represent an aqueous solution at two...Ch. 13 - Prob. 13.42QPCh. 13 - Prob. 13.43QPCh. 13 - Write the equation representing Raoults law, and...Ch. 13 - Prob. 13.45QPCh. 13 - Write the equations relating boiling-point...Ch. 13 - Prob. 13.47QPCh. 13 - Prob. 13.48QPCh. 13 - What is osmosis? What is a semipermeable membrane?Ch. 13 - Prob. 13.50QPCh. 13 - Prob. 13.51QPCh. 13 - Prob. 13.52QPCh. 13 - What are ion pairs? What effect does ion-pair...Ch. 13 - Prob. 13.54QPCh. 13 - Prob. 13.55QPCh. 13 - Prob. 13.56QPCh. 13 - Prob. 13.57QPCh. 13 - The vapor pressure of benzene is 100.0 mmHg at...Ch. 13 - The vapor pressures of ethanol (C2H5OH) and...Ch. 13 - The vapor pressure of ethanol (C2H5OH) at 20C is...Ch. 13 - Prob. 13.61QPCh. 13 - What arc the boiling point and freezing point of a...Ch. 13 - Prob. 13.63QPCh. 13 - How many liters of the antifreeze ethylene glycol...Ch. 13 - Prob. 13.65QPCh. 13 - Prob. 13.66QPCh. 13 - What are the normal freezing points and boiling...Ch. 13 - At 25C, the vapor pressure of pure water is 23.76...Ch. 13 - Both NaCl and CaCl2 are used to melt ice on roads...Ch. 13 - A 0.86 percent by mass solution of NaCl is called...Ch. 13 - Prob. 13.71QPCh. 13 - Calculate the osmotic pressure of a 0.0500 M MgSO4...Ch. 13 - The tallest trees known are the redwoods in...Ch. 13 - Calculate the difference in osmotic pressure (in...Ch. 13 - Prob. 13.75QPCh. 13 - Consider two aqueous solutions, one of sucrose...Ch. 13 - Arrange the following solutions in order of...Ch. 13 - Prob. 13.78QPCh. 13 - Indicate which compound in each of the following...Ch. 13 - Describe how you would use freezing-point...Ch. 13 - Prob. 13.81QPCh. 13 - The elemental analysis of an organic solid...Ch. 13 - A solution of 2.50 g of a compound having the...Ch. 13 - The molar mass of benzoic acid (C6H5COOH)...Ch. 13 - A solution containing 0.8330 g of a polymer of...Ch. 13 - Prob. 13.86QPCh. 13 - A solution of 6.S5 g of a carbohydrate m 100.0 g...Ch. 13 - A 0.036-M aqueous nitrous acid (HNO2) solution has...Ch. 13 - Prob. 13.89QPCh. 13 - Prob. 13.90QPCh. 13 - Prob. 13.91QPCh. 13 - Prob. 13.92QPCh. 13 - Prob. 13.93QPCh. 13 - Lysozyme is an enzyme that cleaves bacterial cell...Ch. 13 - The blood sugar (glucose) level of a diabetic...Ch. 13 - Trees in cold climates may be subjected to...Ch. 13 - Prob. 13.97QPCh. 13 - Two liquids A and B have vapor pressures of 76 and...Ch. 13 - Determine the van't Hoff factor of Na3PO4 in a...Ch. 13 - Prob. 13.100QPCh. 13 - Consider the three mercury manometers shown in the...Ch. 13 - A forensic chemist is given a white powder for...Ch. 13 - Prob. 13.103QPCh. 13 - A solution of 1.00 g of anhydrous aluminum...Ch. 13 - Explain why reverse osmosis is (theoretically)...Ch. 13 - What masses of sodium chloride, magnesium...Ch. 13 - The osmotic pressure of blood plasma is...Ch. 13 - Prob. 13.108QPCh. 13 - A protein has been isolated as a salt with the...Ch. 13 - A nonvolatile organic compound Z was used to make...Ch. 13 - Prob. 13.111QPCh. 13 - State which of the alcohols listed in Problem...Ch. 13 - Before a carbonated beverage bottle is sealed, it...Ch. 13 - Iodine (I2) is only sparingly soluble in water...Ch. 13 - (a) The root cells of plants contain a solution...Ch. 13 - Hemoglobin, the oxygen-transport protein, binds...Ch. 13 - Prob. 13.117QPCh. 13 - In the apparatus shown, what will happen if the...Ch. 13 - Concentrated hydrochloric acid is usually...Ch. 13 - Explain each of the following statements: (a) The...Ch. 13 - Prob. 13.121QPCh. 13 - A 1.32-g sample of a mixture of cyclohexane...Ch. 13 - How does each of the following affect the...Ch. 13 - A solution contains two volatile liquids A and B....Ch. 13 - Prob. 13.125QPCh. 13 - A mixture of ethanol and 1-propanol behaves...Ch. 13 - Ammonia (NH3) is very soluble in water, but...Ch. 13 - For ideal solutions, the volumes are additive....Ch. 13 - Acetic acid is a weak acid that ionizes in...Ch. 13 - Which vitamins (sec the given structures) do you...Ch. 13 - Calculate the percent by mass of the solute in...Ch. 13 - Acetic acid is a polar molecule and can form...Ch. 13 - Prob. 13.133QPCh. 13 - Fish in the Antarctic Ocean swim in water at about...Ch. 13 - Why are ice cubes (e.g., those you see in the...Ch. 13 - Prob. 13.136QPCh. 13 - Two beakers are placed in a closed container...Ch. 13 - (a) Derive the equation relating the molality (m)...Ch. 13 - At 27C, the vapor pressure of pure water is 23.76...Ch. 13 - A very long pipe is capped at one end with a...Ch. 13 - A mixture of liquids A and B exhibits ideal...Ch. 13 - Use Henrys law and the ideal gas equation to prove...Ch. 13 - Prob. 13.143QPCh. 13 - Prob. 13.144QPCh. 13 - The diagram here shows vapor pressure curves for...Ch. 13 - Valinomycin is an antibiotic. It functions by...Ch. 13 - Prob. 13.147QPCh. 13 - Prob. 13.148QPCh. 13 - Prob. 13.149QPCh. 13 - Explain why we cannot use osmotic pressure to...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forwardPredict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forwardPredict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forward
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forward
- give example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward2-Propanone and ethyllithium are mixed and subsequently acid hydrolyzed. Draw and name the structures of the products.arrow_forward(Methanesulfinyl)methane is reacted with NaH, and then with acetophenone. Draw and name the structures of the products.arrow_forward
- 3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forwardWhat is the reason of the following(use equations if possible) a.) In MO preperation through diazotization: Addition of sodium nitrite in acidfied solution in order to form diazonium salt b.) in MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at low pH c.) In MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at pH 4.5 d.) Avoiding not cooling down the reaction mixture when preparing the diazonium salt e.) Cbvcarrow_forwardA 0.552-g sample of an unknown acid was dissolved in water to a total volume of 20.0 mL. This sample was titrated with 0.1103 M KOH. The equivalence point occurred at 29.42 mL base added. The pH of the solution at 10.0 mL base added was 3.72. Determine the molar mass of the acid. Determine the Ka of the acid.arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY