Given Structure to be predicted as either cis or trans isomer. Concept Introduction: Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space. Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side. Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

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Answer 1

Question

Chapter 13, Problem 13.49AP

(a)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

(b)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

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The beta-lactamase hydrolyzes the lactam-ring in penicillin. Describe the mechanism of hydrolysis, insuring to include the involvement of S, D, & K in the reaction sequence. Please help

To map the active site of beta-lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine. Why doesn't D in this hexapeptide not participate in the hydrolysis of the beta-lactam ring even though S, K, and D are involved in the catalyst?

To map the active site of -lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine. Using the experimental results described above derive the primary sequence of the active site hexapeptide. Please help!

Answer 2

Question

Chapter 13, Problem 13.49AP

(a)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

(b)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

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Answer 3

Question

Chapter 13, Problem 13.49AP

(a)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

(b)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

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Answer 4

Question

Chapter 13, Problem 13.49AP

(a)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

(b)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

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Answer 5

Chapter 13, Problem 13.49AP

(a)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

(b)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

Answer 6

Chapter 13, Problem 13.49AP

(a)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

Answer 7

Chapter 13, Problem 13.49AP

(a)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given Structure to be predicted as either cis or trans isomer.

Concept Introduction:

Stereoisomers: A compound has same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

Cis-isomer: In cis-configuration, the two identical substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two identical substituents of the double bond are on the opposite side and the term is included before the name as prefix.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 13.2 - Prob. 13.1P Ch. 13.2 - Prob. 13.2P Ch. 13.2 - What are the IUPAC names of the two alkenes shown...Ch. 13.3 - Prob. 13.4P Ch. 13.3 - Prob. 13.5P Ch. 13.3 - Prob. 13.6KCP Ch. 13.5 - Prob. 13.7P Ch. 13.5 - Many biological transformations can be simply...Ch. 13.5 - (a) After the reaction of 11-cis-retinal with...Ch. 13.5 - Prob. 13.2CIAP

Solution Summary: The author explains that stereoisomers have the same molecular formula but differ in the spatial arrangement of atoms or groups in 3D-space.

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Chapter 13 Solutions