Resonance contributors for the given radical has to be drawn. Concept introduction: Radical or free radical: Unpaired valence electron of an atom, molecule, or ion is called as radical. Resonance: Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

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Answer 1

Question

Chapter 12.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(b)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(c)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(d)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

Answer 2

Question

Chapter 12.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(b)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(c)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(d)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

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Answer 3

Question

Chapter 12.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(b)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(c)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(d)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

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Answer 4

Question

Chapter 12.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(b)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(c)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(d)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Expert Solution & Answer

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Answer 5

Chapter 12.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(b)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(c)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

(d)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 6

Chapter 12.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 7

Chapter 12.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Resonance contributors for the given radical has to be drawn.

Concept introduction:

Radical or free radical:

Unpaired valence electron of an atom, molecule, or ion is called as radical.

Resonance:

Resonance is a way of describing delocalized electrons within certain molecules where the bonding cannot be expressed by one single Lewis structure.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12.2 - Prob. 1P Ch. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3P Ch. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6P Ch. 12.5 - Prob. 8P Ch. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12P Ch. 12.7 - Prob. 13P

Solution Summary: Concept introduction: Radical or free radical: Unpaired valence electron of an atom, molecule, or ion is called as radical. Resonance is a way of describing delocalized electrons within certain

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