To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone . Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

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1. Which pair of aldehydes can lead to the following product? 10% NaOH(aq) OH H 2 moles of propanal ethanal + butanal 2 moles of ethanal ethanal + propanal

Explain how the electrophilic substitution sequences for synthesizing the following compounds from phenol.

b) The Wolf-Kishner reduction is a reaction used in Organic Chemistry to convert carbonyl functionalities into methylene group. The reaction was used to convert an aldehyde or ketone to an alkane using hydrazine, base and thermal conditions. The mechanism begins with the attack of hydrazine of the aldehyde or ketone. Stage 1: The reaction of aldehyde/ketone with hydrazine to produce hydrazine Stage 2: Reaction with the base and heat to convert hydrozone to alkane Write the mechanism of the reaction.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Expert Solution & Answer

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Answer 5

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Answer 6

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 7

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 8

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 9

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 10

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 11

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 12

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 13

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 14

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 15

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 16

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Answer 17

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 12.1 - Prob. 1LTS Ch. 12.1 - Prob. 1PTS Ch. 12.1 - Prob. 2ATS Ch. 12.1 - Prob. 3CC Ch. 12.2 - Prob. 4CC Ch. 12.3 - Prob. 8CC Ch. 12.3 - Prob. 9CC Ch. 12.4 - Prob. 3LTS Ch. 12.4 - Prob. 10PTS Ch. 12.4 - Prob. 11ATS

Solution Summary: The author explains that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

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