EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
Question
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Chapter 12, Problem 65IP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (b)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(d)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (e)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (f)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(g)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(h)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(i)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(j)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(k)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (l)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (m)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (n)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(o)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (p)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(q)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(r)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(s)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

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Students have asked these similar questions
11. Complete the following esterification reaction with names of all the reactants and products under. Hint: Remove the water and end up with ester R-C-OH + ROH R-C-OR + H₂O A carboxylic acid An alcohol An ester Water BYJU'S H-C-C O-H Нин C-C-C-H HAAA H O-C-C-C-H AAA Ethanoic acid Propanol Water Propyl ethanoate By com CH3COOH + CH3CH2CH2CH₂CH₂OH → Practice for alcohols aldehydes and ketones: 12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone: a. 4-methyl cyclohexanone b. 3-methyl-2-pentenal c. 2,3-dimethylcyclohexanone d. 1,3propanediol or Propane 1,3 diol 13. Write systematic names for the following compounds identify functional group: a. b. (CH3)2CH-C OH c) CH(CH₂)-- OH -,-,
may you please show all steps! i am having a hard time understanding and applying in this format, thank you!
10. Complete the substitution reaction of 2 pentanol with these reagents. Reagents & Reaction Conditions use practice sheet. Please write only major products, minor product like water, other gases are not required. Hint: In substitution of alcohol, we generally substitute OH group with Halogens like cl, Br, F using some reagent containing halogens. Ensure to add halogens to the same carbon number where you are removing OH from Examples Alcohols can be converted to Alkyl Halides with HX acids HBr H₂O HCI + H₂O HI + H₂O CH,CH₂OH + SOCI₂ CH,CH₂OH + PCI₁₂ A BBYJU'S CH CHCI + SO₂+ HCI CH₂CH CIP(OH), + HCI CH,CH₂OH + PCI CHCHCI + POCI + HCI CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr 1. Reaction with HBr with 2 Pentanol 2.Reaction with HI with 2 pentanol © Byjus.com 3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role) 4.Reaction with SOCI,, with 2 Pentanol 5.Reaction with PBr; or PCl, with 2 pentanol
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