The product obtained when given ketone is treated with Grignard reagent is to be determined. Concept Introduction: A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 14CC

a)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

b)

Interpretation Introduction

Interpretation :

The product obtained by treating aldehyde with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

c)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

d)

Interpretation Introduction

Interpretation :

The product obtained when given aldehyde is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 14CC

a)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

b)

Interpretation Introduction

Interpretation :

The product obtained by treating aldehyde with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

c)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

d)

Interpretation Introduction

Interpretation :

The product obtained when given aldehyde is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 14CC

a)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

b)

Interpretation Introduction

Interpretation :

The product obtained by treating aldehyde with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

c)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

d)

Interpretation Introduction

Interpretation :

The product obtained when given aldehyde is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 14CC

a)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

b)

Interpretation Introduction

Interpretation :

The product obtained by treating aldehyde with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

c)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

d)

Interpretation Introduction

Interpretation :

The product obtained when given aldehyde is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

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Answer 5

Chapter 12.6, Problem 14CC

a)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

b)

Interpretation Introduction

Interpretation :

The product obtained by treating aldehyde with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

c)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

d)

Interpretation Introduction

Interpretation :

The product obtained when given aldehyde is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 6

Chapter 12.6, Problem 14CC

a)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 7

Chapter 12.6, Problem 14CC

a)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 8

b)

Interpretation Introduction

Interpretation :

The product obtained by treating aldehyde with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 9

b)

Interpretation Introduction

Interpretation :

The product obtained by treating aldehyde with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 10

c)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 11

c)

Interpretation Introduction

Interpretation :

The product obtained when given ketone is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 12

d)

Interpretation Introduction

Interpretation :

The product obtained when given aldehyde is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 13

d)

Interpretation Introduction

Interpretation :

The product obtained when given aldehyde is treated with Grignard reagent is to be determined.

Concept Introduction:

A ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol, respectively. The primary alcohol is produced because of the interaction with formaldehyde.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12.1 - Prob. 1LTS Ch. 12.1 - Prob. 1PTS Ch. 12.1 - Prob. 2ATS Ch. 12.1 - Prob. 3CC Ch. 12.2 - Prob. 4CC Ch. 12.3 - Prob. 8CC Ch. 12.3 - Prob. 9CC Ch. 12.4 - Prob. 3LTS Ch. 12.4 - Prob. 10PTS Ch. 12.4 - Prob. 11ATS

Solution Summary: The author explains how ketone or aldehyde undergoes the Grignard reaction when an organomagnesium halide is added to produce secondary alcohol or tertiary alcohol.

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