To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone . Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

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CHEM2323 E Tt PS CH03 Draw and name all monobromo derivatives of pentane, C5H11Br. Problem 3-33 Name: Draw structures for the following: (a) 2-Methylheptane (d) 2,4,4-Trimethylheptane Problem 3-35 (b) 4-Ethyl-2,2-dimethylhexane (e) 3,3-Diethyl-2,5-dimethylnonane (c) 4-Ethyl-3,4-dimethyloctane 2 (f) 4-Isopropyl-3-methylheptane KNIE>

Problem 3-42 Consider 2-methylbutane (isopentane). Sighting along the C2-C3 bond: (a) Draw a Newman projection of the most stable conformation. (b) Draw a Newman projection of the least stable conformation. Problem 3-44 Construct a qualitative potential-energy diagram for rotation about the C-C bond of 1,2-dibromoethane. Which conformation would you expect to be most stable? Label the anti and gauche conformations of 1,2- dibromoethane. Problem 3-45 Which conformation of 1,2-dibromoethane (Problem 3-44) would you expect to have the largest dipole moment? The observed dipole moment of 1,2-dibromoethane is µ = 1.0 D. What does this tell you about the actual conformation of the molecule?

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Expert Solution & Answer

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Answer 5

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Answer 6

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 7

Chapter 12.6, Problem 15PTS

(a)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 8

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 9

(b)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methylpent-2-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 10

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 11

(c)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 12

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 13

(d)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 1-phenyl-2-butanol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 14

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 15

(e)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 3-methylheptan-3-ol starting from an aldehyde or ketone.

Concept Introduction: The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules to know its method of preparation.

Answer 16

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Answer 17

(f)

Interpretation Introduction

Interpretation: To show that Grignard reagent can be used to make 2-methyl-1,3-diphenylpropan-2-ol starting from an aldehyde or ketone.

Concept Introduction:

The formation of a given compound can be done by using a process known as retrosynthesis. It is a method in which the target molecule is deconstructed into simple molecules in order to know its method of preparation.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 12.1 - Prob. 1LTS Ch. 12.1 - Prob. 1PTS Ch. 12.1 - Prob. 2ATS Ch. 12.1 - Prob. 3CC Ch. 12.2 - Prob. 4CC Ch. 12.3 - Prob. 8CC Ch. 12.3 - Prob. 9CC Ch. 12.4 - Prob. 3LTS Ch. 12.4 - Prob. 10PTS Ch. 12.4 - Prob. 11ATS

Solution Summary: The author explains that Grignard reagent can be used to make 2-pentanol starting from an aldehyde or ketone.

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