
(a)
Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.
Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.
(b)
Interpretation: The reagents required for the transformation of the following compound are to be determined.
Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired

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Chapter 12 Solutions
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
- Ppplllleeeaaasssseeee hellppp wiithhh thisss physical chemistryyyyy I talked like this because AI is very annoyingarrow_forwardFor this question, if the product is racemic, input both enantiomers in the same Marvin editor. A) Input the number that corresponds to the reagent which when added to (E)-but-2-ene will result in a racemic product. Input 1 for Cl, in the cold and dark Input 2 for Oy followed by H₂O, Zn Input 3 for D₂ with metal catalyst Input 4 for H₂ with metal catalyst B) Draw the skeletal structure of the major organic product made from the reagent in part A Marvin JS Help Edit drawing C) Draw the skeletal structure of the major organic product formed when (2)-but-2-ene is treated with peroxyacetic acid. Marvin 35 Helparrow_forwardMichael Reactions 19.52 Draw the products from the following Michael addition reactions. 1. H&C CH (a) i 2. H₂O* (b) OEt (c) EtO H₂NEt (d) ΕΙΟ + 1. NaOEt 2. H₂O' H H 1. NaOEt 2. H₂O*arrow_forward
- Rank the labeled protons (Ha-Hd) in order of increasing acidity, starting with the least acidic. НОН НЬ OHd Онсarrow_forwardCan the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left? ? starting material target If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area. Be sure you follow the standard ALEKS rules for submitting syntheses. + More... Note for advanced students: you may assume that you are using a large excess of benzene as your starting material. C :0 T Add/Remove step Garrow_forwardThe following equations represent the formation of compound MX. What is the AH for the electron affinity of X (g)? X₂ (g) → 2X (g) M (s) → M (g) M (g) M (g) + e- AH = 60 kJ/mol AH = 22 kJ/mol X (g) + e-X (g) M* (g) +X (g) → MX (s) AH = 118 kJ/mol AH = ? AH = -190 kJ/mol AH = -100 kJ/mol a) -80 kJ b) -30 kJ c) -20 kJ d) 20 kJ e) 156 kJarrow_forward
- A covalent bond is the result of the a) b) c) d) e) overlap of two half-filled s orbitals overlap of a half-filled s orbital and a half-filled p orbital overlap of two half-filled p orbitals along their axes parallel overlap of two half-filled parallel p orbitals all of the abovearrow_forwardCan the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left? starting material target If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area. Be sure you follow the standard ALEKS rules for submitting syntheses. + More... Note for advanced students: you may assume that you are using a large excess of benzene as your starting material. C T Add/Remove step X ноarrow_forwardWhich one of the following atoms should have the largest electron affinity? a) b) c) d) 으으 e) 1s² 2s² 2p6 3s¹ 1s² 2s² 2p5 1s² 2s² 2p 3s² 3p² 1s² 2s 2p 3s² 3p6 4s2 3ds 1s² 2s² 2p6arrow_forward
- All of the following are allowed energy levels except _. a) 3f b) 1s c) 3d d) 5p e) 6sarrow_forwardA student wants to make the following product in good yield from a single transformation step, starting from benzene. Add any organic reagents the student is missing on the left-hand side of the arrow, and any addition reagents that are necessary above or below the arrow. If this product can't be made in good yield with a single transformation step, check the box below the drawing area. Note for advanced students: you may assume that an excess of benzene is used as part of the reaction conditions. : ☐ + I X This product can't be made in a single transformation step.arrow_forwardPredict the major products of this organic reaction:arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

