(a) Interpretation: The structural formula of 2,2-dimethylbutane should be determined. Concept Introduction: Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula C n H 2 n + 2 . Rules of drawing structures of alkanes are: First identify the base name, and then draw the straight chain of carbon atoms according to the base name. After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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Answer 1

Question

Chapter 12.4, Problem 12.12P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 2,2-dimethylbutane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 6-butyl-3-methyldecane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 4,4,5,5-tetramethylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of 3-ethyl-5-propylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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1. Base on this experimental results, how do you know that the product which you are turning in is methyl 3-nitrobenzoate(meta substituted product ) rather than either of the other two products? 2. What observation suggests that at least a small amount of one or both of the other two isomers are in the mother liquor?

Explain Huckel's rule.

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Answer 2

Question

Chapter 12.4, Problem 12.12P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 2,2-dimethylbutane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 6-butyl-3-methyldecane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 4,4,5,5-tetramethylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of 3-ethyl-5-propylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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Answer 3

Question

Chapter 12.4, Problem 12.12P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 2,2-dimethylbutane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 6-butyl-3-methyldecane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 4,4,5,5-tetramethylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of 3-ethyl-5-propylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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Answer 4

Question

Chapter 12.4, Problem 12.12P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 2,2-dimethylbutane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 6-butyl-3-methyldecane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 4,4,5,5-tetramethylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of 3-ethyl-5-propylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

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Answer 5

Chapter 12.4, Problem 12.12P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 2,2-dimethylbutane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(b)

Interpretation:

The structural formula of 6-butyl-3-methyldecane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(c)

Interpretation:

The structural formula of 4,4,5,5-tetramethylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Interpretation Introduction

(d)

Interpretation:

The structural formula of 3-ethyl-5-propylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 6

Chapter 12.4, Problem 12.12P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 2,2-dimethylbutane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 7

Chapter 12.4, Problem 12.12P

Interpretation Introduction

(a)

Interpretation:

The structural formula of 2,2-dimethylbutane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structural formula of 6-butyl-3-methyldecane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structural formula of 6-butyl-3-methyldecane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structural formula of 4,4,5,5-tetramethylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structural formula of 4,4,5,5-tetramethylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structural formula of 3-ethyl-5-propylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structural formula of 3-ethyl-5-propylnonane should be determined.

Concept Introduction:

Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula CnH2n+2.

Rules of drawing structures of alkanes are:

First identify the base name, and then draw the straight chain of carbon atoms according to the base name.

After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12.1 - How many hydrogen atoms are present in each...Ch. 12.1 - Which formulas represent acyclic alkanes and which...Ch. 12.2 - Are the compounds in each pair constitutional...Ch. 12.2 - Draw two isomers with molecular formula C6H14 that...Ch. 12.2 - Prob. 12.3P Ch. 12.2 - Classify the carbon atoms in each compound as 1°,...Ch. 12.2 - Prob. 12.4P Ch. 12.2 - Prob. 12.5P Ch. 12.2 - Prob. 12.6P Ch. 12.2 - Prob. 12.7P

Solution Summary: The author explains how the structural formula of 2,2-dimethylbutane should be determined.

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