The mechanism of the given reaction is to be provided. Concept introduction: Carbonyl groups of esters react with two equivalents of Grignard reagents and followed by hydrolysis to produce tertiary alcohols. The initial product formed between Grignard reagent and carbonyl ester is unstable. This complex structure loses magnesium, bromine, and alkoxide to form a ketone . The ketone is highly reactive with Grignard reagent, compared to esters. The ketone reacts immediately with the remaining Grignard reagent. This intermediate product is hydrolyzed to form tertiary alcohols.

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 8PP

Interpretation Introduction

Interpretation:

The mechanism of the given reaction is to be provided.

Concept introduction:

Carbonyl groups of esters react with two equivalents of Grignard reagents and followed by hydrolysis to produce tertiary alcohols. The initial product formed between Grignard reagent and carbonyl ester is unstable. This complex structure loses magnesium, bromine, and alkoxide to form a ketone. The ketone is highly reactive with Grignard reagent, compared to esters. The ketone reacts immediately with the remaining Grignard reagent. This intermediate product is hydrolyzed to form tertiary alcohols.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 8PP

Interpretation Introduction

Interpretation:

The mechanism of the given reaction is to be provided.

Concept introduction:

Carbonyl groups of esters react with two equivalents of Grignard reagents and followed by hydrolysis to produce tertiary alcohols. The initial product formed between Grignard reagent and carbonyl ester is unstable. This complex structure loses magnesium, bromine, and alkoxide to form a ketone. The ketone is highly reactive with Grignard reagent, compared to esters. The ketone reacts immediately with the remaining Grignard reagent. This intermediate product is hydrolyzed to form tertiary alcohols.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 8PP

Interpretation Introduction

Interpretation:

The mechanism of the given reaction is to be provided.

Concept introduction:

Carbonyl groups of esters react with two equivalents of Grignard reagents and followed by hydrolysis to produce tertiary alcohols. The initial product formed between Grignard reagent and carbonyl ester is unstable. This complex structure loses magnesium, bromine, and alkoxide to form a ketone. The ketone is highly reactive with Grignard reagent, compared to esters. The ketone reacts immediately with the remaining Grignard reagent. This intermediate product is hydrolyzed to form tertiary alcohols.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 8PP

Interpretation Introduction