11th Edition

ISBN: 9781118133576

Author: T. W. Graham Solomons, Craig Fryhle

Publisher: Wiley, John & Sons, Incorporated

Concept explainers

Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and…

Epoxides

Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic…

Williamson Ether Synthesis

An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction…

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Textbook Question

Chapter 12, Problem 15P

Write reaction conditions and the product from Swern oxidation of the following compounds.

Chapter 12, Problem 15P, 12.13 Write reaction conditions and the product from Swern oxidation of the following

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Chapter 12, Problem 14P

Chapter 12, Problem 16P

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2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJ

Chapter 12 Solutions

Organic Chemistry

Ch. 12 - Prob. 3PP Ch. 12 - PRACTICE PROBLEM Assign oxidation states to each...Ch. 12 - Prob. 2PP Ch. 12 - PRACTICE PROBLEM 12.4 What oxidation product would...Ch. 12 - Prob. 5PP Ch. 12 - PRACTICE PROBLEM 12.4 Predict the products of the...Ch. 12 - Prob. 7PP Ch. 12 - Prob. 8PP Ch. 12 - Practice Problem 12.7 Provide retrosynthetic...Ch. 12 - Prob. 10PP

Ch. 12 - What products would you expect from the reaction...Ch. 12 - What products would you expect from the reaction...Ch. 12 - What product (or products) would be formed from...Ch. 12 - Prob. 14P Ch. 12 - 12.13 Write reaction conditions and the product...Ch. 12 - Prob. 16P Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the major organic product from each of the...Ch. 12 - 12.21 Predict the major organic product from each...Ch. 12 - 12.22 Predict the product of the following...Ch. 12 - Synthesize each of the following compounds from...Ch. 12 - Prob. 24P Ch. 12 - 21. Write a mechanism for the following reaction....Ch. 12 - Prob. 26P Ch. 12 - Prob. 27P Ch. 12 - 23. What organic products A-H would you expect...Ch. 12 - Prob. 29P Ch. 12 - Show how 1-pentanol could be transformed into each...Ch. 12 - Provide the reagents needed to accomplish...Ch. 12 - Prob. 32P Ch. 12 - For each of the following alcohols, write a...Ch. 12 - Prob. 34P Ch. 12 - Prob. 35P Ch. 12 - Prob. 36P Ch. 12 - Prob. 37P Ch. 12 - 34. Synthesize the following compound using...Ch. 12 - 37. Explain how and IR spectroscopy could be used...Ch. 12 - 12.40 When sucrose (common table sugar) is treated...Ch. 12 - 38. An unknown X shows a broad absorption band in...Ch. 12 - Prob. 1LGP Ch. 12 - Which of the following could be employed to...Ch. 12 - Prob. 2Q Ch. 12 - 12.3 Supply the missing reagents. Ch. 12 - 12.4 Supply the missing reagents and...Ch. 12 - Supply the missing starting compound.

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