Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 12, Problem 32P
Interpretation Introduction

Interpretation:

The synthesis of each of the given compounds is to be shown and a retrosynthesis analysis for each reaction to be written.

Concept introduction:

Retrosynthesis is a technique in which the functional groups present in the product are used to predict the possible reactants by tracing the reaction in the backward direction.

Aldehydes can be formed from primary alcohols by mild oxidation using PCC, while ketones can be formed from secondary alcohols by using oxidants like chromic acid.

Alcohols react with phosphorus bromide to form alkyl bromides.

The Grignard reagent or RMgX is a reagent, which can be prepared from alkyl halide and magnesium in ether. It adds on the alkyl group to carbonyl moiety and converts aldehydes or ketones to alcohols. The reaction of cyanides with RMgX forms ketones. It reacts with carbon dioxide to form a carboxylic acid.

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Chapter 12 Solutions

Organic Chemistry

Ch. 12 - What products would you expect from the reaction...Ch. 12 - What products would you expect from the reaction...Ch. 12 - What product (or products) would be formed from...Ch. 12 - Prob. 14PCh. 12 - 12.13 Write reaction conditions and the product...Ch. 12 - Prob. 16PCh. 12 - Predict the organic product from each of the...Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the major organic product from each of the...Ch. 12 - 12.21 Predict the major organic product from each...Ch. 12 - 12.22 Predict the product of the following...Ch. 12 - Synthesize each of the following compounds from...Ch. 12 - Prob. 24PCh. 12 - 21. Write a mechanism for the following reaction....Ch. 12 - Prob. 26PCh. 12 - Prob. 27PCh. 12 - 23. What organic products A-H would you expect...Ch. 12 - Prob. 29PCh. 12 - Show how 1-pentanol could be transformed into each...Ch. 12 - Provide the reagents needed to accomplish...Ch. 12 - Prob. 32PCh. 12 - For each of the following alcohols, write a...Ch. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - 34. Synthesize the following compound using...Ch. 12 - 37. Explain how and IR spectroscopy could be used...Ch. 12 - 12.40 When sucrose (common table sugar) is treated...Ch. 12 - 38. An unknown X shows a broad absorption band in...Ch. 12 - Prob. 1LGPCh. 12 - Which of the following could be employed to...Ch. 12 - Prob. 2QCh. 12 - 12.3 Supply the missing reagents. Ch. 12 - 12.4 Supply the missing reagents and...Ch. 12 - Supply the missing starting compound.
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