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Interpretation:
The reagent for the given reaction sequence should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Elimination: Two substituents are removed from the molecule in a single step is called E2 elimination. Formation of alkene from tosylation of alcohol through elimination reaction
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides aldehyde.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
Reduction reaction: Reduction is the loss of oxygen atom or addition of hydrogen from a molecule.
Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a
Hydroboration-oxidation
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Chapter 12 Solutions
ORGANIC CHEMISTRY-STD.WILEY PLUS CARD
- option choice: Isoleucine Histidine Threonine Alanine Lysine Aspartate Tryptophan Tyrosine Leucine Arginine Cysteine Asparagine Valine Glutamine Glycine Methionine Serine Proline Phenylalanine Glutamatearrow_forwardsketch the nature of the metal-alkylidene bonding interactions.arrow_forwardPart C The perspective formula of isoleucine, an amino acid, is provided below. HOOC H₂NIC H 川 CH3 CH,CH3 Draw the Newman projection in staggered conformation for isoleucine by viewing the molecule along the C-2-C-3 bond. 1. Edit the Newman projection on the canvas. 2. Replace the appropriate hydrogens with the appropriate -CH3 or other groups. 3. If you need to start over, Undo or choose a Newman projection from the Templates toolbar (bottom). Important: Never delete the hydrogen atoms or bonds directly attached to the template, and do not move them by dragging or dropping them. That will break the projections structures. Only replace them! ▸ View Available Hint(s) 0 2 H± 3D EXP. L ד י CONT. 2 H 0 N оarrow_forward
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