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(a)
Interpretation:
The product for the given reaction should be identified.
Concept introduction:
Ozonolysis: The unsaturated bonds like
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides
Reduction:
Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol
(b)
Interpretation:
The product for the given reaction should be identified.
Concept introduction:
Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol
(c)
Interpretation:
The product for the given reaction should be identified.
Concept introduction:
Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol
(d)
Interpretation:
The product for the given reaction should be identified.
Concept introduction:
Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol
(e)
Interpretation:
The product for the given reaction should be identified.
Concept introduction:
Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol
(f)
Interpretation:
The product for the given reaction should be identified.
Concept introduction:
Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol
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Chapter 12 Solutions
ORGANIC CHEMISTRY-STD.WILEY PLUS CARD
- Check all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forwardFrom the given compound, choose the proton that best fits each given description. a CH2 CH 2 Cl b с CH2 F Most shielded: (Choose one) Least shielded: (Choose one) Highest chemical shift: (Choose one) Lowest chemical shift: (Choose one) ×arrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 1H NMR spectrum? Note: A multiplet is considered one signal.arrow_forward
- For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither. Compound m/z of M* peak m/z of M + 2 peak ratio of M+ : M + 2 peak Which element is present? A 122 no M + 2 peak not applicable (Choose one) B 78 80 3:1 (Choose one) C 227 229 1:1 (Choose one)arrow_forwardShow transformation from reactant to product, step by step. *see imagearrow_forwardCheck the box if the molecule contains the listed item. *See imagearrow_forward
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- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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