ORGANIC CHEMISTRY-STD.WILEY PLUS CARD
3rd Edition
ISBN: 9781119340515
Author: Klein
Publisher: WILEY
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Question
Chapter 12, Problem 39PP
Interpretation Introduction
Interpretation:
The reason for the oxidation reaction of minor hydrated product of 1 methyl cyclohexene should be explained.
Concept introduction:
Markovnikov’s rule: unsymmetrical
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Germanium (Ge) is a semiconductor with a bandgap of 2.2 eV. How could you dope Ge to make it a p-type semiconductor with a larger bandgap?
Group of answer choices
It is impossible to dope Ge and have this result in a larger bandgap.
Dope the Ge with silicon (Si)
Dope the Ge with gallium (Ga)
Dope the Ge with phosphorus (P)
Chapter 12 Solutions
ORGANIC CHEMISTRY-STD.WILEY PLUS CARD
Ch. 12.1 - Prob. 1LTSCh. 12.1 - PRACTICE the skill
Provide an IUPAC name for each...Ch. 12.1 - Safer alternatives to existing insecticides and...Ch. 12.1 - Prob. 3CCCh. 12.2 - Prob. 4CCCh. 12.2 - Prob. 2LTSCh. 12.2 - Prob. 5PTSCh. 12.2 - Flavonoids are a class of naturally occurring...Ch. 12.3 - Prob. 7CCCh. 12.3 - Prob. 8CC
Ch. 12.4 - Prob. 3LTSCh. 12.4 - Prob. 9PTSCh. 12.4 - Prob. 10ATSCh. 12.4 - Prob. 4LTSCh. 12.4 - Prob. 11PTSCh. 12.4 - Prob. 12ATSCh. 12.6 - Prob. 5LTSCh. 12.6 - Prob. 13PTSCh. 12.6 - Prob. 14PTSCh. 12.7 - Prob. 16CCCh. 12.9 - Prob. 6LTSCh. 12.9 - Prob. 17PTSCh. 12.9 - Prob. 18ATSCh. 12.9 - Prob. 19CCCh. 12.10 - Prob. 7LTSCh. 12.10 - PRACTICE the skill
Predict the major organic...Ch. 12.10 - Prob. 21ATSCh. 12.13 - Prob. 8LTSCh. 12.13 - Prob. 22PTSCh. 12.13 - Prob. 23ATSCh. 12.13 - Prob. 24CCCh. 12.13 - Prob. 9LTSCh. 12.13 - Prob. 25PTSCh. 12.13 - Prob. 26ATSCh. 12 - Prob. 27PPCh. 12 - Prob. 28PPCh. 12 - Prob. 29PPCh. 12 - Prob. 30PPCh. 12 - Prob. 31PPCh. 12 - Predict the major product of the reaction between...Ch. 12 - Prob. 33PPCh. 12 - Prob. 34PPCh. 12 - Using a Grignard reaction, show how you could...Ch. 12 - Each of the following alcohols can be prepared via...Ch. 12 - Prob. 37PPCh. 12 - Prob. 38PPCh. 12 - Prob. 39PPCh. 12 - Prob. 40PPCh. 12 - Prob. 41PPCh. 12 - Prob. 42PPCh. 12 - Prob. 43PPCh. 12 - Prob. 44PPCh. 12 - Prob. 45PPCh. 12 - Prob. 46PPCh. 12 - Prob. 47PPCh. 12 - Prob. 48PPCh. 12 - Prob. 49PPCh. 12 - Prob. 50PPCh. 12 - Prob. 51IPCh. 12 - Prob. 52IPCh. 12 - Prob. 53IPCh. 12 - Prob. 54IPCh. 12 - Prob. 55IPCh. 12 - Prob. 56IPCh. 12 - Prob. 57IPCh. 12 - Prob. 58IPCh. 12 - Prob. 59IPCh. 12 - Prob. 60IPCh. 12 - Prob. 61IPCh. 12 - Prob. 62IPCh. 12 - Prob. 63IPCh. 12 - Prob. 64IPCh. 12 - Prob. 65IPCh. 12 - The compound duryne was one of several...Ch. 12 - Estragole is an insect repellant that has been...Ch. 12 - Prob. 68IPCh. 12 - Prob. 70IPCh. 12 - Prob. 71IPCh. 12 - Prob. 72IPCh. 12 - Prob. 73IPCh. 12 - Prob. 74IPCh. 12 - Prob. 75CPCh. 12 - Prob. 76CPCh. 12 - Prob. 77CP
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