General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Textbook Question
Chapter 12, Problem 49E
An 80.0 g piece of dry ice,
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Indicate the type of bond that is considered to be a hydrogen bond.(A). Permanent dipole-dipole interaction between polar molecules.(B). Mixed ionic-covalent bond.(C). Principal interatomic bond(D). Van del Waals forces.
Retro aldol:
NaOH
H₂O
H
NaOH
& d
H₂O
H
Draw the product of the reaction
shown below. Ignore inorganic
byproducts.
H
conc. HBr
Drawing
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Chapter 12 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 12 - For each of the following substances describe the...Ch. 12 - When another atom or group of atoms is substituted...Ch. 12 - Prob. 3ECh. 12 - Arrange the liquids represented by the following...Ch. 12 - One of the following substances is a liquid at...Ch. 12 - In which of the following compound might...Ch. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10E
Ch. 12 - Silicone oils, such as H3C[SiO(CH2)2],Si(CH3) ,...Ch. 12 - Surface tension, viscosity, and vapor pressure are...Ch. 12 - Is there any scientific basis for the colloquial...Ch. 12 - A television commercial claims that a product...Ch. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Carbon tetrachloride (CCl4) and mercury have...Ch. 12 - As a liquid evaporated from an open container, its...Ch. 12 - Prob. 20ECh. 12 - The enthalpy of vaporization of benzene, C6H6(l)...Ch. 12 - A vapor volume of 1.17 L forms when a sample of...Ch. 12 - Use data from the Integrative Example (page 566)...Ch. 12 - How much heat is required to raise the temperature...Ch. 12 - How many liters of CH4(g) , measured at 23.4 °C...Ch. 12 - A 50.0 g piece of iron at 152°C is dropped into...Ch. 12 - From Figure 12-18, estimate (a) the vapor pressure...Ch. 12 - Prob. 28ECh. 12 - Equilibrium is established between Br2(l) and...Ch. 12 - Prob. 30ECh. 12 - A double boiler is used when a careful control of...Ch. 12 - One popular demonstration in chemistry labs is...Ch. 12 - Pressure cookers achieve a high cooking...Ch. 12 - Prob. 34ECh. 12 - A 25.0 L volume of He(g) at 30.0°C is passed...Ch. 12 - A 7.53 L sample of N2 (g) at 742 mmHg and 45.0 °C...Ch. 12 - Prob. 37ECh. 12 - A 10.0 g sample of liquid water is sealed in a...Ch. 12 - Cyclohexanol has a vapor pressure of 10.0 mmHg at...Ch. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Benzaldehyde, C2H2CHO , has a normal boiling point...Ch. 12 - With reference to Figure 12-20, which is the more...Ch. 12 - Which substances listed in Table 12.6 can exist as...Ch. 12 - Prob. 46ECh. 12 - The normal melting point of copper is 1357 K, and...Ch. 12 - An ice calorimeter measures quantities of heat by...Ch. 12 - An 80.0 g piece of dry ice, CO2 (s), is placed in...Ch. 12 - Sketch a plausible phase diagram for hydrazine...Ch. 12 - Shown here is a portion of the phase diagram for...Ch. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Use appropriate phase diagrams data from Table...Ch. 12 - Prob. 56ECh. 12 - To an insulated container with 100.0 g H2O(l) at...Ch. 12 - A 54 cm2 ice cube at 25.0 °C is added to a...Ch. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Silicon carbide, SiC, crystallizes in a form...Ch. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Use Coulomb's law (see Appendix B) to verify the...Ch. 12 - The hardness of crystals is rated based on Mohs...Ch. 12 - Will the mineral villaumite (NaF) or periclase...Ch. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Consider the two-dimensional lattice shown here....Ch. 12 - As we saw in Section 12-6, stacking spheres always...Ch. 12 - Tungsten has a body-centered cubic crystal...Ch. 12 - Magnesium crystallizes in the hcp arrangement...Ch. 12 - Polonium (Po) is the only element known to take on...Ch. 12 - Prob. 76ECh. 12 - Silicon tetrafluoride molecules are arranged in a...Ch. 12 - Two views, a top and side view, for the unit cell...Ch. 12 - Show that the unit cells for CaF2 and TiO2 in...Ch. 12 - Prob. 80ECh. 12 - The crystal structure of magnesium oxide, MgO, is...Ch. 12 - Potassium chloride has the same crystal structure...Ch. 12 - Prob. 83ECh. 12 - Use data from Figure 9-9 to predict the type of...Ch. 12 - Without doing calculations, indicate how you would...Ch. 12 - Determine the lattice energy of KF(s) from the...Ch. 12 - Refer to Example 12-12. Together with data given...Ch. 12 - Prob. 88ECh. 12 - Prob. 89IAECh. 12 - Prob. 90IAECh. 12 - Prob. 91IAECh. 12 - Use the following data and data from Appendix D to...Ch. 12 - Prob. 93IAECh. 12 - Prob. 94IAECh. 12 - Because solid p-dichlorobenzene, C6H4CI2 ,...Ch. 12 - A 1.05 mol sample of H2O(g) is compressed into a...Ch. 12 - Prob. 97IAECh. 12 - By the method used to graph Figure 12-20, plot In...Ch. 12 - Prob. 99IAECh. 12 - Prob. 100IAECh. 12 - Prob. 101IAECh. 12 - Prob. 102IAECh. 12 - In acetic acid vapor, some molecules exist as...Ch. 12 - Prob. 104IAECh. 12 - Sketched here are two hypothetical phase diagrams...Ch. 12 - Prob. 106IAECh. 12 - The triple point temperature of bismuth is 544.5 K...Ch. 12 - The crystal structure of lithium sulfide ( Li2S ),...Ch. 12 - Refer to Figure 12-44 and Figure 12-48. Suppose...Ch. 12 - Prob. 110IAECh. 12 - One way to describe ionic crystal structures is in...Ch. 12 - Prob. 112IAECh. 12 - The enthalpy of formation of Nal(s) is 288 kJ...Ch. 12 - Prob. 114IAECh. 12 - A crystalline solid contains three types of ions,...Ch. 12 - A certain mineral has a cubic unit cell with...Ch. 12 - Prob. 117IAECh. 12 - In some barbecue grills the electric lighter...Ch. 12 - Prob. 119IAECh. 12 - Prob. 120IAECh. 12 - Intermolecular forces play vital and varied roles...Ch. 12 - Prob. 122FPCh. 12 - Prob. 123FPCh. 12 - All solids contain defects or imperfections of...Ch. 12 - In an ionic crystal lattice each cation will be...Ch. 12 - Prob. 126FPCh. 12 - Prob. 127FPCh. 12 - Prob. 128SAECh. 12 - Briefly describe each of the following phenomena...Ch. 12 - Explain the important distinctions between each...Ch. 12 - Prob. 131SAECh. 12 - Prob. 132SAECh. 12 - Prob. 133SAECh. 12 - Prob. 134SAECh. 12 - Prob. 135SAECh. 12 - Prob. 136SAECh. 12 - Prob. 137SAECh. 12 - Prob. 138SAECh. 12 - Prob. 139SAECh. 12 - Prob. 140SAECh. 12 - Prob. 141SAECh. 12 - Prob. 142SAECh. 12 - Prob. 143SAECh. 12 - Prob. 144SAECh. 12 - The following data are given for CCl4 . Normal...Ch. 12 - The fcc unit cell is a cube with atoms at each of...Ch. 12 - Prob. 147SAECh. 12 - Prob. 148SAECh. 12 - Prob. 149SAECh. 12 - Prob. 150SAECh. 12 - In the lithium iodide crystal, the Li—l distance...Ch. 12 - Prob. 152SAECh. 12 - Prob. 153SAECh. 12 - Prob. 154SAECh. 12 - Construct a concept map showing the ideas...
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- Calculate the atomic packing factor of diamond knowing that the number of Si atoms per cm3 is 2.66·1022 and that the atomic radii of silicon and oxygen are, respectively, 0.038 and 0.117 nm.arrow_forwardA pdf file of your hand drawn, stepwise mechanisms for the reactions. For each reaction in the assignment, you must write each mechanism three times (there are 10 reactions, so 30 mechanisms). (A) do the work on a tablet and save as a pdf., it is expected to write each mechanism out and NOT copy and paste the mechanism after writing it just once. Everything should be drawn out stepwise and every bond that is formed and broken in the process of the reaction, and is expected to see all relevant lone pair electrons and curved arrows. Aldol: NaOH HO H Δ NaOH Δarrow_forwardNonearrow_forward
- Draw structures corresponding to the following names and give IUPAC names for the following compounds: (8 Point) a) b) c) CH3 CH2CH3 CH3CHCH2CH2CH CH3 C=C H3C H H2C=C=CHCH3 d) CI e) (3E,5Z)-2,6-Dimethyl-1,3,5,7-octatetraene f) (Z)-4-bromo-3-methyl-3-penten-1-yne g) cis-1-Bromo-2-ethylcyclopentane h) (5R)-4,4,5-trichloro-3,3-dimethyldecanearrow_forwardNonearrow_forwardReview: Design a total total synthesis synthesis of the following compound using methyloxacyclopropane and any other necessary reagents.arrow_forward
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