General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 12, Problem 117IAE
Interpretation Introduction
Interpretation:
The ratio of cation to anion in CaF2 needs to be determined. An alternative structure for CaF2 needs to be suggested to confirm the calculated value.
Concept introduction:
Radius ratio of Ca2+ cation to F- anion can be calculated from their ionic radii. Based on the ratio, void where the cation is more preferably placed can be chosen. Based on that, a structure prediction can be done.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Please help me answer the questions in the photo given below. Thank You so Much and God Bless You More.
Taking into account both the primary intermolecular force and polarizability, arrange the molecules in
order of increasing strength of attraction between them.
H
H
:Br:
:Br:
小玉木林
H
H
H
H
H
Br:
:Br
Br:
H
:CI:
: Br:
: Br:
Substance A
A
2S03(g) →2SO2(g) + O2(g); AH° =
Chapter 12 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 12 - For each of the following substances describe the...Ch. 12 - When another atom or group of atoms is substituted...Ch. 12 - Prob. 3ECh. 12 - Arrange the liquids represented by the following...Ch. 12 - One of the following substances is a liquid at...Ch. 12 - In which of the following compound might...Ch. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10E
Ch. 12 - Silicone oils, such as H3C[SiO(CH2)2],Si(CH3) ,...Ch. 12 - Surface tension, viscosity, and vapor pressure are...Ch. 12 - Is there any scientific basis for the colloquial...Ch. 12 - A television commercial claims that a product...Ch. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Carbon tetrachloride (CCl4) and mercury have...Ch. 12 - As a liquid evaporated from an open container, its...Ch. 12 - Prob. 20ECh. 12 - The enthalpy of vaporization of benzene, C6H6(l)...Ch. 12 - A vapor volume of 1.17 L forms when a sample of...Ch. 12 - Use data from the Integrative Example (page 566)...Ch. 12 - How much heat is required to raise the temperature...Ch. 12 - How many liters of CH4(g) , measured at 23.4 °C...Ch. 12 - A 50.0 g piece of iron at 152°C is dropped into...Ch. 12 - From Figure 12-18, estimate (a) the vapor pressure...Ch. 12 - Prob. 28ECh. 12 - Equilibrium is established between Br2(l) and...Ch. 12 - Prob. 30ECh. 12 - A double boiler is used when a careful control of...Ch. 12 - One popular demonstration in chemistry labs is...Ch. 12 - Pressure cookers achieve a high cooking...Ch. 12 - Prob. 34ECh. 12 - A 25.0 L volume of He(g) at 30.0°C is passed...Ch. 12 - A 7.53 L sample of N2 (g) at 742 mmHg and 45.0 °C...Ch. 12 - Prob. 37ECh. 12 - A 10.0 g sample of liquid water is sealed in a...Ch. 12 - Cyclohexanol has a vapor pressure of 10.0 mmHg at...Ch. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Benzaldehyde, C2H2CHO , has a normal boiling point...Ch. 12 - With reference to Figure 12-20, which is the more...Ch. 12 - Which substances listed in Table 12.6 can exist as...Ch. 12 - Prob. 46ECh. 12 - The normal melting point of copper is 1357 K, and...Ch. 12 - An ice calorimeter measures quantities of heat by...Ch. 12 - An 80.0 g piece of dry ice, CO2 (s), is placed in...Ch. 12 - Sketch a plausible phase diagram for hydrazine...Ch. 12 - Shown here is a portion of the phase diagram for...Ch. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Use appropriate phase diagrams data from Table...Ch. 12 - Prob. 56ECh. 12 - To an insulated container with 100.0 g H2O(l) at...Ch. 12 - A 54 cm2 ice cube at 25.0 °C is added to a...Ch. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Silicon carbide, SiC, crystallizes in a form...Ch. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Use Coulomb's law (see Appendix B) to verify the...Ch. 12 - The hardness of crystals is rated based on Mohs...Ch. 12 - Will the mineral villaumite (NaF) or periclase...Ch. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Consider the two-dimensional lattice shown here....Ch. 12 - As we saw in Section 12-6, stacking spheres always...Ch. 12 - Tungsten has a body-centered cubic crystal...Ch. 12 - Magnesium crystallizes in the hcp arrangement...Ch. 12 - Polonium (Po) is the only element known to take on...Ch. 12 - Prob. 76ECh. 12 - Silicon tetrafluoride molecules are arranged in a...Ch. 12 - Two views, a top and side view, for the unit cell...Ch. 12 - Show that the unit cells for CaF2 and TiO2 in...Ch. 12 - Prob. 80ECh. 12 - The crystal structure of magnesium oxide, MgO, is...Ch. 12 - Potassium chloride has the same crystal structure...Ch. 12 - Prob. 83ECh. 12 - Use data from Figure 9-9 to predict the type of...Ch. 12 - Without doing calculations, indicate how you would...Ch. 12 - Determine the lattice energy of KF(s) from the...Ch. 12 - Refer to Example 12-12. Together with data given...Ch. 12 - Prob. 88ECh. 12 - Prob. 89IAECh. 12 - Prob. 90IAECh. 12 - Prob. 91IAECh. 12 - Use the following data and data from Appendix D to...Ch. 12 - Prob. 93IAECh. 12 - Prob. 94IAECh. 12 - Because solid p-dichlorobenzene, C6H4CI2 ,...Ch. 12 - A 1.05 mol sample of H2O(g) is compressed into a...Ch. 12 - Prob. 97IAECh. 12 - By the method used to graph Figure 12-20, plot In...Ch. 12 - Prob. 99IAECh. 12 - Prob. 100IAECh. 12 - Prob. 101IAECh. 12 - Prob. 102IAECh. 12 - In acetic acid vapor, some molecules exist as...Ch. 12 - Prob. 104IAECh. 12 - Sketched here are two hypothetical phase diagrams...Ch. 12 - Prob. 106IAECh. 12 - The triple point temperature of bismuth is 544.5 K...Ch. 12 - The crystal structure of lithium sulfide ( Li2S ),...Ch. 12 - Refer to Figure 12-44 and Figure 12-48. Suppose...Ch. 12 - Prob. 110IAECh. 12 - One way to describe ionic crystal structures is in...Ch. 12 - Prob. 112IAECh. 12 - The enthalpy of formation of Nal(s) is 288 kJ...Ch. 12 - Prob. 114IAECh. 12 - A crystalline solid contains three types of ions,...Ch. 12 - A certain mineral has a cubic unit cell with...Ch. 12 - Prob. 117IAECh. 12 - In some barbecue grills the electric lighter...Ch. 12 - Prob. 119IAECh. 12 - Prob. 120IAECh. 12 - Intermolecular forces play vital and varied roles...Ch. 12 - Prob. 122FPCh. 12 - Prob. 123FPCh. 12 - All solids contain defects or imperfections of...Ch. 12 - In an ionic crystal lattice each cation will be...Ch. 12 - Prob. 126FPCh. 12 - Prob. 127FPCh. 12 - Prob. 128SAECh. 12 - Briefly describe each of the following phenomena...Ch. 12 - Explain the important distinctions between each...Ch. 12 - Prob. 131SAECh. 12 - Prob. 132SAECh. 12 - Prob. 133SAECh. 12 - Prob. 134SAECh. 12 - Prob. 135SAECh. 12 - Prob. 136SAECh. 12 - Prob. 137SAECh. 12 - Prob. 138SAECh. 12 - Prob. 139SAECh. 12 - Prob. 140SAECh. 12 - Prob. 141SAECh. 12 - Prob. 142SAECh. 12 - Prob. 143SAECh. 12 - Prob. 144SAECh. 12 - The following data are given for CCl4 . Normal...Ch. 12 - The fcc unit cell is a cube with atoms at each of...Ch. 12 - Prob. 147SAECh. 12 - Prob. 148SAECh. 12 - Prob. 149SAECh. 12 - Prob. 150SAECh. 12 - In the lithium iodide crystal, the Li—l distance...Ch. 12 - Prob. 152SAECh. 12 - Prob. 153SAECh. 12 - Prob. 154SAECh. 12 - Construct a concept map showing the ideas...
Knowledge Booster
Similar questions
- What is the relationship between the structures of buckminsterfullerene and carbon nanotubes?arrow_forwardSilane SiH4, phosphine (PH3), and hydrogen sulfide (H2S) melt at 185 C, 133 C, and 85 C, respectively. What does this suggest about the polar character and intermolecular attractions of the three compounds?arrow_forwardExplain why liquids assume the shape of any container into which they are poured, whereas solids are rigid and retain their shape.arrow_forward
- Nanotechnology, or technology utilizing 1100 nm sized particles, has rapidly expanded in the past few decades, with potential applications ranging across far-reaching fields such as electronics, medicine, biomaterials, and consumer products, to name a few. One of the primary advantages of nanoparticles is the presence of large surface/mass ratios, resulting in enhanced surface activities compared to bulk materials. a Use the density of silver (10.49 g/cm3) to determine the number of Ag atoms in a spherical 20.-nm silver particle. b In the crystalline metallic environment, the measured radii of silver atoms has been measured to be 144 pm. Use this to calculate the atomic packing fraction of a 20.-nm silver particle. In other words, calculate the ratio of the volume taken up by Ag atoms to the volume of the entire nanoparticle. c Based on the result of part (b), silver conforms to which type of cubic crystal lattice? A simple cubic B body-centered cubic C face-centered cubic d A cubic Ag ingot having a mass of 5.0-g is processed to form a batch of 20.-nm Ag nanoparticles. Calculate the ratio of the surface area provided by the batch of nanoparticles to the surface area of the initial cube of Ag.arrow_forwardPotassium bromide has the same lattice structure as NaCl. Given the ionic radii of K+ (133 pm) and Br (196 pm), calculate the density of KBr.arrow_forwardIn which of these substances is hydrogen bonding likely to play an important role in determining physical properties: methane 1CH42, hydrazine 1H2NNH22, methyl fluoride 1CH3F2, hydrogen sulfide 1H2S2?arrow_forward
- Name the type(s) of intermolecular forces that exists between molecules (or basic units) in each of the following species: (a) LiF, (b) CH4, (c) SO2 (a) benzene (C6H6), (b) CH3Cl, (c) PF3, (d) NaCl, (e) CS2arrow_forwardName the type(s) of intermolecular forces that exists between molecules (or basic units) in each of the following species and identify the following species that are capable of hydrogen-bonding among themselves. (a) BeH2, (b) CH3COOHarrow_forward8. Which member of the following pairs has the larger London dispersion forces: (a) H2O or H2S; (b) CO2 or CO; (c) CH4 or CCl4?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning