Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition
Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition
3rd Edition
ISBN: 9780134255644
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition, Chapter 12, Problem 45P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition, Chapter 12, Problem 45P , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition, Chapter 12, Problem 45P , additional homework tip  3

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition, Chapter 12, Problem 45P , additional homework tip  4

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93 = Volume 93 = 5.32× 10 3 -23 ст a √ 1073 5.32× 10 3 cm³

Chapter 12 Solutions

Essential Organic Chemistry Study Guide & Solution Manual, Books a la Carte Edition

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