GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES

4th Edition

ISBN: 9781265982959

Author: SMITH

Publisher: MCG

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Textbook Question

Chapter 12, Problem 27P

Classify each carbon as 1°, 2°, 3°, or 4°.

a. C H 3 ( C H 2 ) 3 C H 3

b. Chapter 12, Problem 27P, Classify each carbon as 1°, 2°, 3°, or 4°. a. CH3(CH2)3CH3 b. c. (CH3)3CC(CH3)3 d. , example 1

c. ( C H 3 ) 3 C C ( C H 3 ) 3

d. Chapter 12, Problem 27P, Classify each carbon as 1°, 2°, 3°, or 4°. a. CH3(CH2)3CH3 b. c. (CH3)3CC(CH3)3 d. , example 2

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Chapter 12, Problem 26P

Chapter 12, Problem 28P

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

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Chapter 12 Solutions

GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES

Ch. 12.1 - How many hydrogen atoms are present in each...Ch. 12.1 - Which formulas represent acyclic alkanes and which...Ch. 12.2 - Are the compounds in each pair constitutional...Ch. 12.2 - Draw two isomers with molecular formula C6H14 that...Ch. 12.2 - Prob. 12.3P Ch. 12.2 - Classify the carbon atoms in each compound as 1°,...Ch. 12.2 - Prob. 12.4P Ch. 12.2 - Prob. 12.5P Ch. 12.2 - Prob. 12.6P Ch. 12.2 - Prob. 12.7P

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Classify each carbon as 1°, 2°, 3°, or 4°. a. C H 3 ( C H 2 ) 3 C H 3 b. c. ( C H 3 ) 3 C C ( C H 3 ) 3 d.

Solution Summary: The author explains the classification of carbon atoms in the following molecule.

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Chapter 12 Solutions