Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 12, Problem 12.92QE
Interpretation Introduction
Interpretation:
The solubilities of potassium perchlorate at
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ
Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this
system:
?
rise
Under these conditions, will the pressure of N2 tend to rise or fall?
☐ x10
fall
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of N2 will tend to rise, can that be
changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of N2 will tend to fall, can that be changed to a tendency to rise
by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
☐
atm
☑
5
00.
18
Ar
Chapter 12 Solutions
Chemistry Principles And Practice
Ch. 12 - Prob. 12.1QECh. 12 - Prob. 12.2QECh. 12 - Prob. 12.3QECh. 12 - Prob. 12.4QECh. 12 - Prob. 12.5QECh. 12 - Prob. 12.6QECh. 12 - Prob. 12.7QECh. 12 - Prob. 12.8QECh. 12 - Prob. 12.9QECh. 12 - Prob. 12.10QE
Ch. 12 - Prob. 12.11QECh. 12 - Prob. 12.12QECh. 12 - Create a flow diagram, similar to those used in...Ch. 12 - Prob. 12.14QECh. 12 - Prob. 12.15QECh. 12 - Prob. 12.16QECh. 12 - Prob. 12.17QECh. 12 - Prob. 12.18QECh. 12 - Prob. 12.19QECh. 12 - Prob. 12.20QECh. 12 - Prob. 12.21QECh. 12 - Prob. 12.22QECh. 12 - Prob. 12.23QECh. 12 - Prob. 12.24QECh. 12 - Prob. 12.25QECh. 12 - Prob. 12.26QECh. 12 - Prob. 12.27QECh. 12 - What is the molality of copper(II) bromide (CuBr2)...Ch. 12 - Prob. 12.29QECh. 12 - Prob. 12.30QECh. 12 - A water solution of sodium hypochlorite (NaOCl) is...Ch. 12 - Prob. 12.32QECh. 12 - Prob. 12.33QECh. 12 - Vinegar is a 5.0% solution of acetic acid...Ch. 12 - Prob. 12.35QECh. 12 - A 2.77 M NaOH solution in water has a density of...Ch. 12 - The density of a 3.75 M aqueous sulfuric acid...Ch. 12 - Prob. 12.40QECh. 12 - Prob. 12.41QECh. 12 - Prob. 12.42QECh. 12 - Predict the relative solubility of each compound...Ch. 12 - Predict the relative solubility of each compound...Ch. 12 - Prob. 12.45QECh. 12 - Prob. 12.46QECh. 12 - Prob. 12.47QECh. 12 - Prob. 12.48QECh. 12 - Prob. 12.49QECh. 12 - The solubility of ethylene (C2H4) in water at 20 C...Ch. 12 - Prob. 12.51QECh. 12 - Prob. 12.52QECh. 12 - Prob. 12.53QECh. 12 - Prob. 12.54QECh. 12 - Prob. 12.55QECh. 12 - Prob. 12.56QECh. 12 - From the data presented in Figure 12.11, determine...Ch. 12 - Prob. 12.58QECh. 12 - Prob. 12.59QECh. 12 - Prob. 12.60QECh. 12 - Prob. 12.61QECh. 12 - Prob. 12.62QECh. 12 - The vapor pressure of chloroform (CHCl3) is 360...Ch. 12 - Prob. 12.64QECh. 12 - Prob. 12.65QECh. 12 - Prob. 12.66QECh. 12 - Prob. 12.67QECh. 12 - Prob. 12.68QECh. 12 - Prob. 12.69QECh. 12 - Prob. 12.70QECh. 12 - A solution of 1.00 g of a protein in 20.0 mL water...Ch. 12 - Prob. 12.72QECh. 12 - Arrange the following aqueous solutions in order...Ch. 12 - Arrange the following solutions in order of...Ch. 12 - Prob. 12.75QECh. 12 - An aqueous solution of sodium bromide freezes at...Ch. 12 - Prob. 12.77QECh. 12 - Prob. 12.78QECh. 12 - Prob. 12.79QECh. 12 - Prob. 12.80QECh. 12 - A 0.029 M solution of potassium sulfate has an...Ch. 12 - The freezing point of a 0.031-m solution of...Ch. 12 - Prob. 12.83QECh. 12 - Prob. 12.84QECh. 12 - Prob. 12.85QECh. 12 - Prob. 12.86QECh. 12 - Prob. 12.87QECh. 12 - Prob. 12.88QECh. 12 - Prob. 12.89QECh. 12 - Prob. 12.90QECh. 12 - Predict the relative solubility of each compound...Ch. 12 - Prob. 12.92QECh. 12 - Prob. 12.94QECh. 12 - Prob. 12.95QECh. 12 - Prob. 12.96QECh. 12 - Sketch graphs of total vapor pressure versus the...Ch. 12 - Prob. 12.98QECh. 12 - Prob. 12.99QECh. 12 - Prob. 12.100QECh. 12 - Prob. 12.101QECh. 12 - Prob. 12.102QECh. 12 - Prob. 12.103QECh. 12 - A 10.00-mL sample of a 24.00% solution of ammonium...Ch. 12 - Prob. 12.105QECh. 12 - In the 1986 Lake Nyos disaster (see the chapter...Ch. 12 - Prob. 12.107QE
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- i need help with the followingarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. atm ☑ 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HCN is a weak acid. acids: 0.29 mol of NaOH is added to 1.0 L of a 1.2M HCN solution. bases: ☑ other: 0.09 mol of HCl is added to acids: 1.0 L of a solution that is bases: 0.3M in both HCN and KCN. other: 0,0,... ? 00. 18 Ar 日arrow_forward
- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1arrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?arrow_forward
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- Identifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ararrow_forwardHighlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area. HO- HO- -0 OH OH HO NG HO- HO- OH OH OH OH NG OHarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY