The number of different three-carbon alkyl groups exist has to be identified. Concept Introduction: Alkyl groups are named according to IUPAC nomenclature . The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups. Rule 1: Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group. Rule 2: Base chain that is identified is numbered in a way beginning at the point of attachment. Rule 3: The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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Answer 1

Question

Chapter 12, Problem 12.92EP

(a)

Interpretation Introduction

Interpretation:

The number of different three-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The number of different six-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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(a) 21.8 Name the following compounds. & (b) Br (e) O₂N. (h) H (c) Br (d) NH2 ☑N Br H ہیں Ph (g) OMe бл .0-0.e 21.9 Draw a structural formula for each compound. (a) 2,3-Dinitrotoluene (c) Diphenylmethanol (e) p-Nitroaniline (b) 3-Propylanisole (d) m-Propylphenol (f) Pentabromobenzene

Answer 2

Question

Chapter 12, Problem 12.92EP

(a)

Interpretation Introduction

Interpretation:

The number of different three-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The number of different six-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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Answer 3

Question

Chapter 12, Problem 12.92EP

(a)

Interpretation Introduction

Interpretation:

The number of different three-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The number of different six-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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Answer 4

Question

Chapter 12, Problem 12.92EP

(a)

Interpretation Introduction

Interpretation:

The number of different three-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The number of different six-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

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Answer 5

Chapter 12, Problem 12.92EP

(a)

Interpretation Introduction

Interpretation:

The number of different three-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

(b)

Interpretation Introduction

Interpretation:

The number of different six-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 6

Chapter 12, Problem 12.92EP

(a)

Interpretation Introduction

Interpretation:

The number of different three-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 7

Chapter 12, Problem 12.92EP

(a)

Interpretation Introduction

Interpretation:

The number of different three-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The number of different six-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The number of different six-carbon alkyl groups exist has to be identified.

Concept Introduction:

Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.

Rule 1:

Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.

Rule 2:

Base chain that is identified is numbered in a way beginning at the point of attachment.

Rule 3:

The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - Prob. 1QQ Ch. 12.1 - Prob. 2QQ Ch. 12.2 - Prob. 1QQ Ch. 12.2 - Prob. 2QQ Ch. 12.3 - Prob. 1QQ Ch. 12.3 - Prob. 2QQ Ch. 12.4 - Prob. 1QQ Ch. 12.4 - Prob. 2QQ Ch. 12.4 - Prob. 3QQ Ch. 12.5 - Prob. 1QQ

Solution Summary: The author explains that three-carbon alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing "-ane" with "yl".

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