Concept explainers
(a)
Interpretation:
The name of the branched alkyl group attached to the carbon chains has to be given.
Concept Introduction:
Alkyl groups are named according to
Rule 1:
Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.
Rule 2:
Base chain that is identified is numbered in a way beginning at the point of attachment.
Rule 3:
The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.
(b)
Interpretation:
The name of the branched alkyl group attached to the carbon chains has to be given.
Concept Introduction:
Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.
Rule 1:
Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.
Rule 2:
Base chain that is identified is numbered in a way beginning at the point of attachment.
Rule 3:
The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.
(c)
Interpretation:
The name of the branched alkyl group attached to the carbon chains has to be given.
Concept Introduction:
Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.
Rule 1:
Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.
Rule 2:
Base chain that is identified is numbered in a way beginning at the point of attachment.
Rule 3:
The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.
(d)
Interpretation:
The name of the branched alkyl group attached to the carbon chains has to be given.
Concept Introduction:
Alkyl groups are named according to IUPAC nomenclature. The name is obtained considering the parent alkane name and replacing “-ane” with “-yl”. In naming branched chain alkyl groups, this becomes little complicated. Hence, IUPAC system for giving name to such larger groups names them by considering as if they were themselves a separate compound. Three rules are followed while naming the larger groups.
Rule 1:
Longest continuous chain which begins at the point of attachment of the alkyl group becomes the base name for the alkyl group.
Rule 2:
Base chain that is identified is numbered in a way beginning at the point of attachment.
Rule 3:
The substituents that are present in the base chain is listed in alphabetical order using the locant as prefixes whenever necessary.
Want to see the full answer?
Check out a sample textbook solution
Chapter 12 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
- 3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forwardWhat is the reason of the following(use equations if possible) a.) In MO preperation through diazotization: Addition of sodium nitrite in acidfied solution in order to form diazonium salt b.) in MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at low pH c.) In MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at pH 4.5 d.) Avoiding not cooling down the reaction mixture when preparing the diazonium salt e.) Cbvcarrow_forwardA 0.552-g sample of an unknown acid was dissolved in water to a total volume of 20.0 mL. This sample was titrated with 0.1103 M KOH. The equivalence point occurred at 29.42 mL base added. The pH of the solution at 10.0 mL base added was 3.72. Determine the molar mass of the acid. Determine the Ka of the acid.arrow_forward
- As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will its major product: 2,0° with a new C-C bond as If this reaction will work, draw the major organic product or products you would expect in the drawing aree below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and desh bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new C-C bond, just check the box under the drawing area and leave it blank.arrow_forwardwrite the mechanism of the nucleophilic acyl substitution reaction, please give an examplearrow_forwardThe compound in the figure is reacted with 10 n-butyllihium, 2° propanone, and 3º H2O. Draw and name the products obtained. SiMe3arrow_forward
- Caffeine (C8H10N4O2, pictured below) is a weak base. The pKb of caffeine is 10.4. What is the pH of a 0.0155 M solution of caffeine?arrow_forward2-Cyclopentyl-2-methyl-1,3-dioxolane is reacted with H₂SO₄. Draw and name the structures of the products.arrow_forwardIndicate the products of the reaction of 1-cyclohexyl-2,2-dimethylpropan-1-one with CH3CO3H (). Draw the structures of the compounds.arrow_forward
- Write chemical equations for: the reaction of benzoic acid chloride with grignard reagent [CH3MgX] the reaction of butanoic acid with methyl amine [CH3NH2]arrow_forward2-(3-Aminopropyl)cyclohexan-1-one is reacted with H₂SO₄. Draw the structures of the products.arrow_forwardPlease help me solve number 2arrow_forward
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
World of ChemistryChemistryISBN:9780618562763Author:Steven S. ZumdahlPublisher:Houghton Mifflin College Div