The possible products containing only one bromine has to be predicted. Concept Introduction: Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases. Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one H at a time is replaced, if allowed to react for a long enough time, all Hydrogen atoms will be replaced with halogens.

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Answer 1

Question

Chapter 12, Problem 12.69CP

a)

Interpretation Introduction

Interpretation:

The possible products containing only one bromine has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one H at a time is replaced, if allowed to react for a long enough time, all Hydrogen atoms will be replaced with halogens.

b)

Interpretation Introduction

Interpretation:

The possible products containing two bromines that are not on the same carbon has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one hydrogen atom at a time is replaced, if allowed to react for a long enough time, all hydrogen atoms will be replaced with halogens.

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Answer 2

Question

Chapter 12, Problem 12.69CP

a)

Interpretation Introduction

Interpretation:

The possible products containing only one bromine has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one H at a time is replaced, if allowed to react for a long enough time, all Hydrogen atoms will be replaced with halogens.

b)

Interpretation Introduction

Interpretation:

The possible products containing two bromines that are not on the same carbon has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one hydrogen atom at a time is replaced, if allowed to react for a long enough time, all hydrogen atoms will be replaced with halogens.

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Answer 3

Question

Chapter 12, Problem 12.69CP

a)

Interpretation Introduction

Interpretation:

The possible products containing only one bromine has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one H at a time is replaced, if allowed to react for a long enough time, all Hydrogen atoms will be replaced with halogens.

b)

Interpretation Introduction

Interpretation:

The possible products containing two bromines that are not on the same carbon has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one hydrogen atom at a time is replaced, if allowed to react for a long enough time, all hydrogen atoms will be replaced with halogens.

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Answer 4

Question

Chapter 12, Problem 12.69CP

a)

Interpretation Introduction

Interpretation:

The possible products containing only one bromine has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one H at a time is replaced, if allowed to react for a long enough time, all Hydrogen atoms will be replaced with halogens.

b)

Interpretation Introduction

Interpretation:

The possible products containing two bromines that are not on the same carbon has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one hydrogen atom at a time is replaced, if allowed to react for a long enough time, all hydrogen atoms will be replaced with halogens.

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Answer 5

Chapter 12, Problem 12.69CP

a)

Interpretation Introduction

Interpretation:

The possible products containing only one bromine has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one H at a time is replaced, if allowed to react for a long enough time, all Hydrogen atoms will be replaced with halogens.

b)

Interpretation Introduction

Interpretation:

The possible products containing two bromines that are not on the same carbon has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one hydrogen atom at a time is replaced, if allowed to react for a long enough time, all hydrogen atoms will be replaced with halogens.

Answer 6

Chapter 12, Problem 12.69CP

a)

Interpretation Introduction

Interpretation:

The possible products containing only one bromine has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one H at a time is replaced, if allowed to react for a long enough time, all Hydrogen atoms will be replaced with halogens.

Answer 7

Chapter 12, Problem 12.69CP

a)

Interpretation Introduction

Interpretation:

The possible products containing only one bromine has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one H at a time is replaced, if allowed to react for a long enough time, all Hydrogen atoms will be replaced with halogens.

Answer 8

b)

Interpretation Introduction

Interpretation:

The possible products containing two bromines that are not on the same carbon has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one hydrogen atom at a time is replaced, if allowed to react for a long enough time, all hydrogen atoms will be replaced with halogens.

Answer 9

b)

Interpretation Introduction

Interpretation:

The possible products containing two bromines that are not on the same carbon has to be predicted.

Concept Introduction:

Free radical stability: As the number of carbon substituents increases, the stability of the free radical increases.

Selectivity determining step: The selectivity determining step is the breakage of the C-H bond by a halogen radical. Only one hydrogen atom at a time is replaced, if allowed to react for a long enough time, all hydrogen atoms will be replaced with halogens.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.2 - Locate and identify the functional groups in (a)...Ch. 12.2 - Draw structures for molecules that fit the...Ch. 12.3 - Prob. 12.3P Ch. 12.3 - There are two branched-chain isomers with the...Ch. 12.4 - Draw the following three isomers of C5H12 as...Ch. 12.4 - Prob. 12.6P Ch. 12.4 - Prob. 12.7P Ch. 12.4 - Draw both condensed and line structures for the...Ch. 12.5 - Which of the following structures represent the...Ch. 12.5 - Are the pairs of compounds shown below the same...

Solution Summary: The author explains that as the number of carbon substituents increases, the stability of the free radical increases. The homolytic cleavage of bromine molecule produces two free highly reactive chlorine radicals.

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