Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 12, Problem 12.5DQ
Interpretation Introduction

Interpretation:

How the internal energy and entropy of a system composed of two levels vary with temperature has to be explained.

Concept Introduction:

Entropy:

Entropy is the measure of randomness of a system. It is the measure of how the molecules are disordered in a system. It is represented by the letter S.

Internal energy:

Internal energy is the sum of the kinetic and potential energies of a system. So, it is the energy that is arising from the positions and interactions of the molecules in a system. It is represented by the letter Q .

Relation between entropy and internal energy:

The mathematical expression for entropy according to the 2nd law of thermodynamics relates the entropy with the internal energy as shown here:

  ΔS=ΔQTΔS=ChangeinEntropyΔQ=Changeininternal energyT=Temperature

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