Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
Question
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Chapter 12, Problem 12B.2E

(a)

Interpretation Introduction

Interpretation:

The translation partition function for N2 molecule from the given data has to be evaluated.

Concept Introduction:

The translation partition function for has the following expression:

qT=(2πmkT)32Vh3

qT=Translationalpartitionfunctionm=Massofthemoleculek=Boltzmannconstant=1.381×10-23JK-1T=Temperature

h=Plank'sconstant=6.626×10-34JsV=Volumeofthemolecule

(b)

Interpretation Introduction

Interpretation:

The translation partition function for CS2 molecule from the given data has to be evaluated.

Concept Introduction:

The translation partition function for has the following expression:

qT=(2πmkT)32Vh3

qT=Translationalpartitionfunctionm=Massofthemoleculek=Boltzmannconstant=1.381×10-23JK-1T=Temperature

h=Plank'sconstant=6.626×10-34JsV=Volumeofthemolecule

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