
Concept explainers
(a)
Interpretation:
With the given data, the ratio of the populations of
Concept Introduction:
The ratio of the population can be found using the Boltzmann distribution formula:
(a)

Answer to Problem 12.1P
With the given data, the ratio of the populations of
Explanation of Solution
Calculating the degeneracy and energy for the given quantum states
The given molecule is
For the quantum level or state
For the quantum level or state
The energy for any of the quantum level
The energy for the quantum level
The energy for the quantum level
The ratio of the population of the levels with
Converting temperature from
Given: The rotational constant is
Therefore, the ratio of the populations of
(b)
Interpretation:
With the given data, the ratio of the populations of
Concept Introduction:
The ratio of the population can be found using the Boltzmann distribution formula:
(b)

Answer to Problem 12.1P
With the given data, the ratio of the populations of
Explanation of Solution
The given molecule is
For the quantum level or state
For the quantum level or state
The energy for any of the quantum level
The energy for the quantum level
The energy for the quantum level
The ratio of the population of the levels with
Converting temperature from
Given: The rotational constant is
Therefore, the ratio of the populations of
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Chapter 12 Solutions
Elements Of Physical Chemistry
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