CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Chapter 12, Problem 12.44SP
The atomic radius of Pb is 175 pm, and the density is 11.34 g/cm3. Does lead have a primitive cubic structure or a face-centered cubic structure?
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4. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted
without ambiguity.
a)
NHBoc
⚫OBn
HO.
H3C
CO2CH3
-OBn
H3C
H3C.
H3C.
NHBOC
CI
CO2CH3
Draw structures of the following compounds and identify their role:
mCPBA
(MCPBA)
DMS
Py
9-BBN
LAH
Sia₂BH
TsCI
PCC
t-BuOK
LDA
MeLi
n-BuLi
DMSO
DMF
Sodium Borohydride
Lithium DiisopropylAmide
2
Using Luther's rule, calculate the reference potential of the Hg2+/Hg redox electrode.
DATA: Electrode potentials E° = 0,854 V y E 0,788 V
Hg2+/Hg
2+
Hg2/Hg
Chapter 12 Solutions
CHEMISTRY-TEXT
Ch. 12 - Calcium metal crystallizes in a cubic...Ch. 12 - Polonium metal crystallizes in a simple cubic...Ch. 12 - Polonium metal crystallizes in a simple cubic...Ch. 12 - The density of a sample of metal "as measured to...Ch. 12 - Zinc sulfide crystallizes in the following cubic...Ch. 12 - Prob. 12.6ACh. 12 - Prob. 12.7PCh. 12 - Prob. 12.8ACh. 12 - Prob. 12.9PCh. 12 - Prob. 12.10A
Ch. 12 - Prob. 12.11PCh. 12 - Prob. 12.12ACh. 12 - Prob. 12.13PCh. 12 - Prob. 12.14PCh. 12 - Prob. 12.15PCh. 12 - Prob. 12.16PCh. 12 - Prob. 12.17PCh. 12 - Identify each of the following kinds of packingCh. 12 - Prob. 12.19CPCh. 12 - Titanium oxide crystallizes in the following cubic...Ch. 12 - Prob. 12.21CPCh. 12 - Prob. 12.22CPCh. 12 - Prob. 12.23CPCh. 12 - Prob. 12.24CPCh. 12 - Prob. 12.25CPCh. 12 - Prob. 12.26SPCh. 12 - Prob. 12.27SPCh. 12 - Prob. 12.28SPCh. 12 - Prob. 12.29SPCh. 12 - Prob. 12.30SPCh. 12 - Prob. 12.31SPCh. 12 - Diffraction of X rays with =154.2 pm at an angle...Ch. 12 - Diffraction of X rays with =154.2 pm at an angle...Ch. 12 - Which of the four kinds of packing used by metals...Ch. 12 - What is a unit cell? How many atoms are in one...Ch. 12 - Copper crystallizes in a face-centered cubic unit...Ch. 12 - Lead crystallizes in a cubic unit cell with anedge...Ch. 12 - Prob. 12.38SPCh. 12 - Tungsten crystallizes in a body-centered cubic...Ch. 12 - Prob. 12.40SPCh. 12 - Prob. 12.41SPCh. 12 - Titanium metal has a density of and an atomic...Ch. 12 - Calcium metal has a density of 1.55 g/cm3 and...Ch. 12 - The atomic radius of Pb is 175 pm, and the density...Ch. 12 - The density of a sample of metal was measured to...Ch. 12 - If a protein can be induced to crystallize, its...Ch. 12 - The molecular structure of a scorpion toxin, a...Ch. 12 - Iron crystallizes in a body-centered cubic unit...Ch. 12 - Silver metal crystallizes in a face-centered cubic...Ch. 12 - Sodium hydride, NaH, crystallizes in a...Ch. 12 - Cesium chloride crystallizers in a cubic unit cell...Ch. 12 - If the edge length of an NaH unit cell is 488 pm,...Ch. 12 - The edge length of a CsCI unit cell (Problem...Ch. 12 - Silicon carbide, SiC, is a covalent network solid...Ch. 12 - Prob. 12.55SPCh. 12 - Prob. 12.56SPCh. 12 - Prob. 12.57SPCh. 12 - Prob. 12.58SPCh. 12 - Prob. 12.59SPCh. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Prob. 12.76SPCh. 12 - Prob. 12.77SPCh. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Prob. 12.80SPCh. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Prob. 12.85SPCh. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - Prob. 12.94SPCh. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Prob. 12.101SPCh. 12 - A photovoltaic cell contains a p-n junction that...Ch. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104SPCh. 12 - Prob. 12.105SPCh. 12 - Prob. 12.106SPCh. 12 - Prob. 12.107SPCh. 12 - Prob. 12.108SPCh. 12 - Prob. 12.109SPCh. 12 - Prob. 12.110SPCh. 12 - Prob. 12.111SPCh. 12 - Prob. 12.112SPCh. 12 - Prob. 12.113SPCh. 12 - Prob. 12.114SPCh. 12 - Prob. 12.115SPCh. 12 - Prob. 12.116SPCh. 12 - Prob. 12.117SPCh. 12 - Prob. 12.118SPCh. 12 - Prob. 12.119SPCh. 12 - Prob. 12.120SPCh. 12 - Prob. 12.121SPCh. 12 - Prob. 12.122SPCh. 12 - Prob. 12.123SPCh. 12 - Prob. 12.124SPCh. 12 - Prob. 12.125SPCh. 12 - Prob. 12.126SPCh. 12 - Prob. 12.127SPCh. 12 - Prob. 12.128SPCh. 12 - Prob. 12.129SPCh. 12 - Prob. 12.130SPCh. 12 - Prob. 12.131SPCh. 12 - Prob. 12.132SPCh. 12 - Prob. 12.133SPCh. 12 - Prob. 12.134MPCh. 12 - Prob. 12.135MPCh. 12 - Prob. 12.136MPCh. 12 - Prob. 12.137MPCh. 12 - Assume that 1588 g of an alkali metal undergoes...Ch. 12 - Prob. 12.139MPCh. 12 - Prob. 12.140MPCh. 12 - Prob. 12.141MPCh. 12 - Prob. 12.142MPCh. 12 - Prob. 12.143MPCh. 12 - Prob. 12.144MP
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- For the following compound: HO -H Draw a mechanism for the tautomerization process under BASIC conditions: Mechanism A: H-O: H-OH H-O HH H-OO Mechanism B: H-Q Mechanism C: Θ OH H-O: Mechanism D: H-O H- H-OO C H-OO H- H- H-OO HH OH -H - HON H :OH H-Harrow_forwardidentify the product (or multiple products) for each of the following reactions: CI 1) NaNH2 (excess) ठ Cl 2) H₂O Hz H₂SO₂, H₂O HgSO Lindlar's catalyst 1) n-BuLi 2) 1)9-BBN 2) H₂O, NaOH ? Br H A B C afó gó H OA B O c OD E OF D E F H H Na, NHarrow_forwardIdentify the product (or multiple products) for each of the following reactions: ? or CI CI 1) NaNHz (excess) 2) H₂O OA OB O C OD OE OF H₂SO₂, H₂O Hq50. 1) n-BuLi 2) Br 1) 9-BBN 2) H₂O₂, NaOH A B H H متته D E H H H H C H H F H H H₂ Lindlar's catalyst Na NHarrow_forward
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