The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

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Answer 1

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Chapter 12, Problem 10PP

(a)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

(b)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

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Draw the complete mechanism for the reaction below. Please include appropriate arrows, intermediates, and formal charges.

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

Answer 2

Question

Chapter 12, Problem 10PP

(a)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

(b)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

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Answer 3

Question

Chapter 12, Problem 10PP

(a)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

(b)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Expert Solution & Answer

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Answer 4

Question

Chapter 12, Problem 10PP

(a)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

(b)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Expert Solution & Answer

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Answer 5

Chapter 12, Problem 10PP

(a)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

(b)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Answer 6

Chapter 12, Problem 10PP

(a)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Answer 7

Chapter 12, Problem 10PP

(a)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Answer 10

Expert Solution & Answer

Answer 11

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Answer 12

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Answer 13

Ch. 12 - Prob. 1QC Ch. 12 - Prob. 2QC Ch. 12 - Prob. 3QC Ch. 12 - Prob. 4QC Ch. 12 - Prob. 5QC Ch. 12 - Prob. 6QC Ch. 12 - Prob. 1PP Ch. 12 - Prob. 2PP Ch. 12 - Prob. 3PP Ch. 12 - Prob. 4PP

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Solution Summary: The author explains that the effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

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The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

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Chapter 12 Solutions

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Solution Summary: The author explains that the effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

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Interpretation: The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Interpretation: The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

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Chapter 12 Solutions

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.

Interpretation:

The effect on the given reaction at equilibrium on decrease in volume of the container is to be determined.