Introduction to Chemistry
Introduction to Chemistry
4th Edition
ISBN: 9780073523002
Author: Rich Bauer, James Birk Professor Dr., Pamela S. Marks
Publisher: McGraw-Hill Education
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Chapter 12, Problem 37QP
Interpretation Introduction

Interpretation:

The reason for the fact that the free chlorine atoms in the stratosphere are dangerous even when they are present in a little amount is to be explained.

Concept Introduction:

Catalysts are the molecules that are used in the reactions to increase its rate without being actually consumed in the reaction.

Catalyst converter is used to reduce the emission from an internal combustion engine. Its main purpose is to catalyze a redox reaction and convert the pollutant in exhaust gases into fewer pollutant gases.

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Devise electrochemical cells in which the following reactions could be made to occur. If liquid junctions are necessary, note them in the cell schematic appropriately, but neglect their effects. (a) H2OH + OH¯ (b) 2H2O2 H₂O (c) 2PbSO4 + 2H2O (d) An TMPD PыO₂+ Pb + 4H+ + 20%¯¯ An + TMPD (in acetonitrile, where An and An are anthracene and its anion radical, and TMPD and TMPD are N,N,N',N'-tetramethyl-p-phenylenediamine and its cation radical. Use anthracene potentials for DMF solutions given in Appendix C.3). (e) 2Ce3+ + 2H + BQ 2Ce4+ + H2Q (aqueous, where BQ is p-benzoquinone and H₂Q is p- hydroquinone) (f) Ag +Agl (aqueous) (g) Fe3+ + Fe(CN)6 Fe²+ + Fe(CN) (aqueous)
Consider each of the following electrode-solution interfaces, and write the equation for the elec- trode reaction that occurs first when the potential is moved in (1) a negative direction and (2) a posi- tive direction from the open-circuit potential. Next to each reaction write the approximate potential for the reaction in V vs. SCE (assuming the reaction is reversible). (a) Pt/Cu2+ (0.01 M), Cd2+ (0.01 M), H2SO4(1 M) (b) Pt/Sn2+ (0.01 M), Sn4+ (0.01 M), HCl(1 M) (c) Hg/Cd2+ (0.01 M), Zn2+ (0.01 M), HCl(1 M)
What are the major products of both of the organic reactions. Please be sure to use wedge and dash bonds to show the stereochemistry of the products if it is needed. Please include the final product as well as a digram/drawing to show the mechanism of the reaction.

Chapter 12 Solutions

Introduction to Chemistry

Ch. 12 - Prob. 5PPCh. 12 - Prob. 6PPCh. 12 - Prob. 7PPCh. 12 - Prob. 8PPCh. 12 - Prob. 9PPCh. 12 - Prob. 10PPCh. 12 - Consider the following equilibrium:...Ch. 12 - Prob. 12PPCh. 12 - Prob. 1QPCh. 12 - Match the key terms with the descriptions...Ch. 12 - Prob. 3QPCh. 12 - Prob. 4QPCh. 12 - Prob. 5QPCh. 12 - Prob. 6QPCh. 12 - Prob. 7QPCh. 12 - Prob. 8QPCh. 12 - Prob. 9QPCh. 12 - Prob. 10QPCh. 12 - Prob. 11QPCh. 12 - Prob. 12QPCh. 12 - Prob. 13QPCh. 12 - Prob. 14QPCh. 12 - Prob. 15QPCh. 12 - Prob. 16QPCh. 12 - Prob. 17QPCh. 12 - Prob. 18QPCh. 12 - Prob. 19QPCh. 12 - Prob. 20QPCh. 12 - Prob. 21QPCh. 12 - Prob. 22QPCh. 12 - Prob. 23QPCh. 12 - Prob. 24QPCh. 12 - Prob. 25QPCh. 12 - Prob. 26QPCh. 12 - Prob. 27QPCh. 12 - Prob. 28QPCh. 12 - Prob. 29QPCh. 12 - Prob. 30QPCh. 12 - Prob. 31QPCh. 12 - Prob. 32QPCh. 12 - Prob. 33QPCh. 12 - Prob. 34QPCh. 12 - Prob. 35QPCh. 12 - Prob. 36QPCh. 12 - Prob. 37QPCh. 12 - Prob. 38QPCh. 12 - Prob. 39QPCh. 12 - Prob. 40QPCh. 12 - Prob. 41QPCh. 12 - Prob. 42QPCh. 12 - Prob. 43QPCh. 12 - Prob. 44QPCh. 12 - Prob. 45QPCh. 12 - Prob. 46QPCh. 12 - Prob. 47QPCh. 12 - Prob. 48QPCh. 12 - Prob. 49QPCh. 12 - Prob. 50QPCh. 12 - Prob. 51QPCh. 12 - Prob. 52QPCh. 12 - Prob. 53QPCh. 12 - Prob. 54QPCh. 12 - Prob. 55QPCh. 12 - Prob. 56QPCh. 12 - Prob. 57QPCh. 12 - Prob. 58QPCh. 12 - Prob. 59QPCh. 12 - Prob. 60QPCh. 12 - Prob. 61QPCh. 12 - Prob. 62QPCh. 12 - Prob. 63QPCh. 12 - Prob. 64QPCh. 12 - Prob. 65QPCh. 12 - Prob. 66QPCh. 12 - Prob. 67QPCh. 12 - Prob. 68QPCh. 12 - Prob. 69QPCh. 12 - Prob. 70QPCh. 12 - Prob. 71QPCh. 12 - Prob. 72QPCh. 12 - Prob. 73QPCh. 12 - Prob. 74QPCh. 12 - Prob. 75QPCh. 12 - Prob. 76QPCh. 12 - Prob. 77QPCh. 12 - Prob. 78QPCh. 12 - Prob. 79QPCh. 12 - Prob. 80QPCh. 12 - Prob. 81QPCh. 12 - Prob. 82QPCh. 12 - Prob. 83QPCh. 12 - Prob. 84QPCh. 12 - Prob. 85QPCh. 12 - Prob. 86QPCh. 12 - Prob. 87QPCh. 12 - Prob. 88QPCh. 12 - Prob. 89QPCh. 12 - Prob. 90QPCh. 12 - Prob. 91QPCh. 12 - Prob. 92QPCh. 12 - Prob. 93QPCh. 12 - Prob. 94QPCh. 12 - Prob. 95QPCh. 12 - Prob. 96QPCh. 12 - Prob. 97QPCh. 12 - Prob. 98QPCh. 12 - Prob. 99QPCh. 12 - Prob. 100QPCh. 12 - Prob. 101QPCh. 12 - Prob. 102QPCh. 12 - Prob. 103QPCh. 12 - Prob. 104QPCh. 12 - Prob. 105QPCh. 12 - Prob. 106QPCh. 12 - Prob. 107QPCh. 12 - Prob. 108QPCh. 12 - Prob. 109QPCh. 12 - Prob. 110QPCh. 12 - Prob. 111QPCh. 12 - Prob. 112QPCh. 12 - Prob. 113QPCh. 12 - Prob. 114QPCh. 12 - Prob. 115QPCh. 12 - Prob. 116QPCh. 12 - Prob. 117QPCh. 12 - Prob. 118QPCh. 12 - Prob. 119QPCh. 12 - Prob. 120QPCh. 12 - Prob. 121QPCh. 12 - Prob. 122QPCh. 12 - Prob. 123QPCh. 12 - Prob. 124QPCh. 12 - Prob. 125QPCh. 12 - Prob. 126QPCh. 12 - Prob. 127QPCh. 12 - Prob. 128QPCh. 12 - Prob. 129QPCh. 12 - Prob. 130QPCh. 12 - Prob. 131QPCh. 12 - Prob. 132QPCh. 12 - Prob. 133QPCh. 12 - Prob. 134QPCh. 12 - Prob. 135QPCh. 12 - Prob. 136QPCh. 12 - Prob. 137QPCh. 12 - Prob. 138QPCh. 12 - Prob. 139QPCh. 12 - Prob. 140QPCh. 12 - Prob. 141QPCh. 12 - Prob. 142QPCh. 12 - Prob. 143QP
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