Introduction to Chemistry
4th Edition
ISBN: 9780073523002
Author: Rich Bauer, James Birk Professor Dr., Pamela S. Marks
Publisher: McGraw-Hill Education
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Chapter 12, Problem 2PP
(a)
Interpretation Introduction
Interpretation:
The effect of temperature increase on the total number of collisions and the fraction of effective collision between molecule A and molecule B is to be determined
(b)
Interpretation Introduction
Interpretation:
The effect of surface area of reactant on the total number of collisions and the fraction of effective collision between molecule A and molecule B is to be determined.
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19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
MeOH
OSO2CH3
MeOH
Chapter 12 Solutions
Introduction to Chemistry
Ch. 12 - Prob. 1QCCh. 12 - Prob. 2QCCh. 12 - Prob. 3QCCh. 12 - Prob. 4QCCh. 12 - Prob. 5QCCh. 12 - Prob. 6QCCh. 12 - Prob. 1PPCh. 12 - Prob. 2PPCh. 12 - Prob. 3PPCh. 12 - Prob. 4PP
Ch. 12 - Prob. 5PPCh. 12 - Prob. 6PPCh. 12 - Prob. 7PPCh. 12 - Prob. 8PPCh. 12 - Prob. 9PPCh. 12 - Prob. 10PPCh. 12 - Consider the following equilibrium:...Ch. 12 - Prob. 12PPCh. 12 - Prob. 1QPCh. 12 - Match the key terms with the descriptions...Ch. 12 - Prob. 3QPCh. 12 - Prob. 4QPCh. 12 - Prob. 5QPCh. 12 - Prob. 6QPCh. 12 - Prob. 7QPCh. 12 - Prob. 8QPCh. 12 - Prob. 9QPCh. 12 - Prob. 10QPCh. 12 - Prob. 11QPCh. 12 - Prob. 12QPCh. 12 - Prob. 13QPCh. 12 - Prob. 14QPCh. 12 - Prob. 15QPCh. 12 - Prob. 16QPCh. 12 - Prob. 17QPCh. 12 - Prob. 18QPCh. 12 - Prob. 19QPCh. 12 - Prob. 20QPCh. 12 - Prob. 21QPCh. 12 - Prob. 22QPCh. 12 - Prob. 23QPCh. 12 - Prob. 24QPCh. 12 - Prob. 25QPCh. 12 - Prob. 26QPCh. 12 - Prob. 27QPCh. 12 - Prob. 28QPCh. 12 - Prob. 29QPCh. 12 - Prob. 30QPCh. 12 - Prob. 31QPCh. 12 - Prob. 32QPCh. 12 - Prob. 33QPCh. 12 - Prob. 34QPCh. 12 - Prob. 35QPCh. 12 - Prob. 36QPCh. 12 - Prob. 37QPCh. 12 - Prob. 38QPCh. 12 - Prob. 39QPCh. 12 - Prob. 40QPCh. 12 - Prob. 41QPCh. 12 - Prob. 42QPCh. 12 - Prob. 43QPCh. 12 - Prob. 44QPCh. 12 - Prob. 45QPCh. 12 - Prob. 46QPCh. 12 - Prob. 47QPCh. 12 - Prob. 48QPCh. 12 - Prob. 49QPCh. 12 - Prob. 50QPCh. 12 - Prob. 51QPCh. 12 - Prob. 52QPCh. 12 - Prob. 53QPCh. 12 - Prob. 54QPCh. 12 - Prob. 55QPCh. 12 - Prob. 56QPCh. 12 - Prob. 57QPCh. 12 - Prob. 58QPCh. 12 - Prob. 59QPCh. 12 - Prob. 60QPCh. 12 - Prob. 61QPCh. 12 - Prob. 62QPCh. 12 - Prob. 63QPCh. 12 - Prob. 64QPCh. 12 - Prob. 65QPCh. 12 - Prob. 66QPCh. 12 - Prob. 67QPCh. 12 - Prob. 68QPCh. 12 - Prob. 69QPCh. 12 - Prob. 70QPCh. 12 - Prob. 71QPCh. 12 - Prob. 72QPCh. 12 - Prob. 73QPCh. 12 - Prob. 74QPCh. 12 - Prob. 75QPCh. 12 - Prob. 76QPCh. 12 - Prob. 77QPCh. 12 - Prob. 78QPCh. 12 - Prob. 79QPCh. 12 - Prob. 80QPCh. 12 - Prob. 81QPCh. 12 - Prob. 82QPCh. 12 - Prob. 83QPCh. 12 - Prob. 84QPCh. 12 - Prob. 85QPCh. 12 - Prob. 86QPCh. 12 - Prob. 87QPCh. 12 - Prob. 88QPCh. 12 - Prob. 89QPCh. 12 - Prob. 90QPCh. 12 - Prob. 91QPCh. 12 - Prob. 92QPCh. 12 - Prob. 93QPCh. 12 - Prob. 94QPCh. 12 - Prob. 95QPCh. 12 - Prob. 96QPCh. 12 - Prob. 97QPCh. 12 - Prob. 98QPCh. 12 - Prob. 99QPCh. 12 - Prob. 100QPCh. 12 - Prob. 101QPCh. 12 - Prob. 102QPCh. 12 - Prob. 103QPCh. 12 - Prob. 104QPCh. 12 - Prob. 105QPCh. 12 - Prob. 106QPCh. 12 - Prob. 107QPCh. 12 - Prob. 108QPCh. 12 - Prob. 109QPCh. 12 - Prob. 110QPCh. 12 - Prob. 111QPCh. 12 - Prob. 112QPCh. 12 - Prob. 113QPCh. 12 - Prob. 114QPCh. 12 - Prob. 115QPCh. 12 - Prob. 116QPCh. 12 - Prob. 117QPCh. 12 - Prob. 118QPCh. 12 - Prob. 119QPCh. 12 - Prob. 120QPCh. 12 - Prob. 121QPCh. 12 - Prob. 122QPCh. 12 - Prob. 123QPCh. 12 - Prob. 124QPCh. 12 - Prob. 125QPCh. 12 - Prob. 126QPCh. 12 - Prob. 127QPCh. 12 - Prob. 128QPCh. 12 - Prob. 129QPCh. 12 - Prob. 130QPCh. 12 - Prob. 131QPCh. 12 - Prob. 132QPCh. 12 - Prob. 133QPCh. 12 - Prob. 134QPCh. 12 - Prob. 135QPCh. 12 - Prob. 136QPCh. 12 - Prob. 137QPCh. 12 - Prob. 138QPCh. 12 - Prob. 139QPCh. 12 - Prob. 140QPCh. 12 - Prob. 141QPCh. 12 - Prob. 142QPCh. 12 - Prob. 143QP
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