General, Organic, and Biochemistry
General, Organic, and Biochemistry
9th Edition
ISBN: 9780078021541
Author: Katherine J Denniston, Joseph J Topping, Dr Danae Quirk Dorr
Publisher: McGraw-Hill Education
Question
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Chapter 11.5, Problem 11.19Q

(a)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

General, Organic, and Biochemistry, Chapter 11.5, Problem 11.19Q , additional homework tip  1

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration.  In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond.  During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

General, Organic, and Biochemistry, Chapter 11.5, Problem 11.19Q , additional homework tip  2

Two cases are possible here.  One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

General, Organic, and Biochemistry, Chapter 11.5, Problem 11.19Q , additional homework tip  3

R1 group being alkyl:

General, Organic, and Biochemistry, Chapter 11.5, Problem 11.19Q , additional homework tip  4

(b)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

General, Organic, and Biochemistry, Chapter 11.5, Problem 11.19Q , additional homework tip  5

Concept Introduction:

Refer part (a).

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Chapter 11 Solutions

General, Organic, and Biochemistry

Ch. 11.3 - Draw each of the cis-trans isomers in Question...Ch. 11.3 - Prob. 11.7QCh. 11.3 - Prob. 11.8QCh. 11.5 - Prob. 11.6PPCh. 11.5 - Prob. 11.7PPCh. 11.5 - Prob. 11.9QCh. 11.5 - Write balanced equations for the hydrogenation of...Ch. 11.5 - Prob. 11.11QCh. 11.5 - Prob. 11.12QCh. 11.5 - Prob. 11.8PPCh. 11.5 - Prob. 11.13QCh. 11.5 - Prob. 11.14QCh. 11.5 - Prob. 11.15QCh. 11.5 - Prob. 11.16QCh. 11.5 - Prob. 11.9PPCh. 11.5 - Prob. 11.17QCh. 11.5 - Prob. 11.18QCh. 11.5 - Prob. 11.19QCh. 11.5 - Prob. 11.20QCh. 11.5 - Write a balanced equation for the hydrobromination...Ch. 11.6 - Name the following compounds using the IUPAC and...Ch. 11.6 - Prob. 11.21QCh. 11.6 - Prob. 11.22QCh. 11 - Prob. 11.23QPCh. 11 - Prob. 11.24QPCh. 11 - Prob. 11.25QPCh. 11 - Prob. 11.26QPCh. 11 - Prob. 11.27QPCh. 11 - Prob. 11.28QPCh. 11 - Prob. 11.29QPCh. 11 - Prob. 11.30QPCh. 11 - Prob. 11.31QPCh. 11 - Prob. 11.32QPCh. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - Prob. 11.39QPCh. 11 - Prob. 11.40QPCh. 11 - Prob. 11.41QPCh. 11 - Prob. 11.42QPCh. 11 - Prob. 11.43QPCh. 11 - Prob. 11.44QPCh. 11 - Prob. 11.45QPCh. 11 - Prob. 11.46QPCh. 11 - Which of the following alkenes can exist as...Ch. 11 - Prob. 11.48QPCh. 11 - Prob. 11.49QPCh. 11 - Prob. 11.50QPCh. 11 - Prob. 11.51QPCh. 11 - Prob. 11.52QPCh. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Prob. 11.57QPCh. 11 - Prob. 11.58QPCh. 11 - Prob. 11.59QPCh. 11 - Prob. 11.60QPCh. 11 - Prob. 11.61QPCh. 11 - Prob. 11.62QPCh. 11 - Prob. 11.63QPCh. 11 - Prob. 11.64QPCh. 11 - Prob. 11.65QPCh. 11 - Prob. 11.66QPCh. 11 - Prob. 11.67QPCh. 11 - Prob. 11.68QPCh. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - Prob. 11.71QPCh. 11 - Prob. 11.72QPCh. 11 - Prob. 11.73QPCh. 11 - Prob. 11.74QPCh. 11 - Prob. 11.75QPCh. 11 - Prob. 11.76QPCh. 11 - Prob. 11.77QPCh. 11 - Prob. 11.78QPCh. 11 - Prob. 11.79QPCh. 11 - Prob. 11.80QPCh. 11 - Prob. 11.81QPCh. 11 - Prob. 11.82QPCh. 11 - Prob. 11.83QPCh. 11 - Write an equation for the addition reaction that...Ch. 11 - Prob. 11.85QPCh. 11 - Draw the structure of each of the following...Ch. 11 - Prob. 11.87QPCh. 11 - Prob. 11.88QPCh. 11 - Prob. 11.89QPCh. 11 - Prob. 11.90QPCh. 11 - Prob. 11.91QPCh. 11 - Prob. 11.92QPCh. 11 - Draw each of the following compounds, using...Ch. 11 - Prob. 11.94QPCh. 11 - Prob. 11.95QPCh. 11 - Prob. 11.96QPCh. 11 - Prob. 11.97QPCh. 11 - Prob. 11.98QPCh. 11 - Prob. 11.99QPCh. 11 - Prob. 11.100QPCh. 11 - Prob. 11.101QPCh. 11 - Prob. 11.102QPCh. 11 - Prob. 11.103QPCh. 11 - What biological molecules contain purine rings? Ch. 11 - Prob. 1CPCh. 11 - Prob. 2CPCh. 11 - Prob. 3CPCh. 11 - Prob. 4CPCh. 11 - Prob. 5CP
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