Equation for complete hydration of the alkyne given has to be written. Concept Introduction: Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone. General structure of alkyne can be given as, Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group. R 1 group being Hydrogen: R 1 group being alkyl:

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11.5, Problem 11.19Q

(a)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Refer part (a).

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from the compound in KBr pellet) and the mass spectrum as shown below. The mass spectrum of compound Tesla showed strong mt peak at 71. TRANSMITTANCE LOD Relative Intensity 100 MS-NW-1539 40 20 80 T 44 55 10 15 20 25 30 35 40 45 50 55 60 65 70 75 m/z D 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11.5, Problem 11.19Q

(a)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Refer part (a).

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11.5, Problem 11.19Q

(a)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Refer part (a).

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11.5, Problem 11.19Q

(a)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Refer part (a).

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Answer 5

Chapter 11.5, Problem 11.19Q

(a)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 11.5, Problem 11.19Q

(a)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

Answer 7

Chapter 11.5, Problem 11.19Q

(a)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

Answer 8

(b)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Refer part (a).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11.2 - Name each of the following alkenes and alkynes...Ch. 11.2 - Prob. 11.2PP Ch. 11.2 - Prob. 11.1Q Ch. 11.2 - Prob. 11.2Q Ch. 11.3 - Prob. 11.3PP Ch. 11.3 - Prob. 11.4PP Ch. 11.3 - Prob. 11.5PP Ch. 11.3 - Prob. 11.3Q Ch. 11.3 - Prob. 11.4Q Ch. 11.3 - Prob. 11.5Q

Interpretation: Equation for complete hydration of the alkyne given has to be written. Concept Introduction: Refer part (a).

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Chapter 11 Solutions

Interpretation:

Equation for complete hydration of the alkyne given has to be written.

Concept Introduction:

Refer part (a).