Given compound has to be named according to IUPAC nomenclature . Concept Introduction: A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary. IUPAC rules for naming alkenes : There are about five rules that has to be followed for naming an alkene and an alkyne . They are, The longest continuous carbon chain in the compound that contains double bond or triple has to be identified. This is known as parent compound. Suffix “–ane” (in name of alkane ) is replaced with “-ene” for alkene or “-yne” for alkyne. Numbering has to be done so that the lowest number is given to the double or triple bond. Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering. If the alkenes have more than one double bond they are called as alkadienes (two double bonds) or alkatrienes (three double bonds). Appropriate suffix has to be used depending on the number of multiple bonds present in the compound. Stereoinformation has to be included in the IUPAC name in the starting. This can be either cis- or trans- for alkene.

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Answer 1

Question

Chapter 11.3, Problem 11.8Q

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkenes:

There are about five rules that has to be followed for naming an alkene and an alkyne. They are,

The longest continuous carbon chain in the compound that contains double bond or triple has to be identified. This is known as parent compound.

Suffix “–ane” (in name of alkane) is replaced with “-ene” for alkene or “-yne” for alkyne.

Numbering has to be done so that the lowest number is given to the double or triple bond.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the alkenes have more than one double bond they are called as alkadienes (two double bonds) or alkatrienes (three double bonds). Appropriate suffix has to be used depending on the number of multiple bonds present in the compound.

Stereoinformation has to be included in the IUPAC name in the starting. This can be either cis- or trans- for alkene.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 11.3, Problem 11.8Q

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkenes:

There are about five rules that has to be followed for naming an alkene and an alkyne. They are,

The longest continuous carbon chain in the compound that contains double bond or triple has to be identified. This is known as parent compound.

Suffix “–ane” (in name of alkane) is replaced with “-ene” for alkene or “-yne” for alkyne.

Numbering has to be done so that the lowest number is given to the double or triple bond.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the alkenes have more than one double bond they are called as alkadienes (two double bonds) or alkatrienes (three double bonds). Appropriate suffix has to be used depending on the number of multiple bonds present in the compound.

Stereoinformation has to be included in the IUPAC name in the starting. This can be either cis- or trans- for alkene.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Expert Solution & Answer

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Answer 3

Question

Chapter 11.3, Problem 11.8Q

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkenes:

There are about five rules that has to be followed for naming an alkene and an alkyne. They are,

The longest continuous carbon chain in the compound that contains double bond or triple has to be identified. This is known as parent compound.

Suffix “–ane” (in name of alkane) is replaced with “-ene” for alkene or “-yne” for alkyne.

Numbering has to be done so that the lowest number is given to the double or triple bond.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the alkenes have more than one double bond they are called as alkadienes (two double bonds) or alkatrienes (three double bonds). Appropriate suffix has to be used depending on the number of multiple bonds present in the compound.

Stereoinformation has to be included in the IUPAC name in the starting. This can be either cis- or trans- for alkene.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

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Answer 4

Question

Chapter 11.3, Problem 11.8Q

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkenes:

There are about five rules that has to be followed for naming an alkene and an alkyne. They are,

The longest continuous carbon chain in the compound that contains double bond or triple has to be identified. This is known as parent compound.

Suffix “–ane” (in name of alkane) is replaced with “-ene” for alkene or “-yne” for alkyne.

Numbering has to be done so that the lowest number is given to the double or triple bond.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the alkenes have more than one double bond they are called as alkadienes (two double bonds) or alkatrienes (three double bonds). Appropriate suffix has to be used depending on the number of multiple bonds present in the compound.

Stereoinformation has to be included in the IUPAC name in the starting. This can be either cis- or trans- for alkene.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Expert Solution & Answer

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Answer 5

Chapter 11.3, Problem 11.8Q

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkenes:

There are about five rules that has to be followed for naming an alkene and an alkyne. They are,

The longest continuous carbon chain in the compound that contains double bond or triple has to be identified. This is known as parent compound.

Suffix “–ane” (in name of alkane) is replaced with “-ene” for alkene or “-yne” for alkyne.

Numbering has to be done so that the lowest number is given to the double or triple bond.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the alkenes have more than one double bond they are called as alkadienes (two double bonds) or alkatrienes (three double bonds). Appropriate suffix has to be used depending on the number of multiple bonds present in the compound.

Stereoinformation has to be included in the IUPAC name in the starting. This can be either cis- or trans- for alkene.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 11.3, Problem 11.8Q

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkenes:

There are about five rules that has to be followed for naming an alkene and an alkyne. They are,

The longest continuous carbon chain in the compound that contains double bond or triple has to be identified. This is known as parent compound.

Suffix “–ane” (in name of alkane) is replaced with “-ene” for alkene or “-yne” for alkyne.

Numbering has to be done so that the lowest number is given to the double or triple bond.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the alkenes have more than one double bond they are called as alkadienes (two double bonds) or alkatrienes (three double bonds). Appropriate suffix has to be used depending on the number of multiple bonds present in the compound.

Stereoinformation has to be included in the IUPAC name in the starting. This can be either cis- or trans- for alkene.

Answer 7

Chapter 11.3, Problem 11.8Q

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkenes:

There are about five rules that has to be followed for naming an alkene and an alkyne. They are,

The longest continuous carbon chain in the compound that contains double bond or triple has to be identified. This is known as parent compound.

Suffix “–ane” (in name of alkane) is replaced with “-ene” for alkene or “-yne” for alkyne.

Numbering has to be done so that the lowest number is given to the double or triple bond.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the alkenes have more than one double bond they are called as alkadienes (two double bonds) or alkatrienes (three double bonds). Appropriate suffix has to be used depending on the number of multiple bonds present in the compound.

Stereoinformation has to be included in the IUPAC name in the starting. This can be either cis- or trans- for alkene.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11.2 - Name each of the following alkenes and alkynes...Ch. 11.2 - Prob. 11.2PP Ch. 11.2 - Prob. 11.1Q Ch. 11.2 - Prob. 11.2Q Ch. 11.3 - Prob. 11.3PP Ch. 11.3 - Prob. 11.4PP Ch. 11.3 - Prob. 11.5PP Ch. 11.3 - Prob. 11.3Q Ch. 11.3 - Prob. 11.4Q Ch. 11.3 - Prob. 11.5Q

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Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

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Chapter 11 Solutions

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Interpretation: Given compound has to be named according to IUPAC nomenclature. Concept Introduction: Refer part (a).

Interpretation: Given compound has to be named according to IUPAC nomenclature. Concept Introduction: Refer part (a).

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Chapter 11 Solutions

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).

Interpretation:

Given compound has to be named according to IUPAC nomenclature.

Concept Introduction:

Refer part (a).