Three expected alcohols that are produced in the S N 1 hydrolysis reaction of the compound shown are to be discussed. Concept Introduction: > For an S N 1 reaction, the reaction follows the first order rate law. In the first step, stable carbocation is formed. > Allylic carbocations can be stabilized by electron delocalization. > The geometry for a carbocation is planar, and thus, a nucleophile can attack from either side of the carbocation that yields more than one products. > The carbon atom which is adjacent to either of the double bonded carbon atoms is the allylic carbon atom. An allylic carbon atom is sp 3 hybridized. > The atoms or groups attached to the allylic carbon atoms are the allylic substituents.

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Chapter 11.2, Problem 4P

Interpretation Introduction

Interpretation:

Three expected alcohols that are produced in the SN1 hydrolysis reaction of the compound shown are to be discussed.

Concept Introduction:
>
For an SN1 reaction, the reaction follows the first order rate law. In the first step, stable carbocation is formed.
>
Allylic carbocations can be stabilized by electron delocalization.
>
The geometry for a carbocation is planar, and thus, a nucleophile can attack from either side of the carbocation that yields more than one products.
>
The carbon atom which is adjacent to either of the double bonded carbon atoms is the allylic carbon atom. An allylic carbon atom is sp3 hybridized.
>
The atoms or groups attached to the allylic carbon atoms are the allylic substituents.

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