A reason behind the betteryield of the substitution product of trans-1-chloro-2-butene than 3-chloro-1-butene is to be discussed. Concept Introduction: > Allyl chlorides have a chlorine atom attached on the carbon atom adjacent to C=C > S N 2 reactions of ally chlorides proceed mainly with substitution rather than elimination. > A good nucleophile exclusively forms the substitution product.When the concentration of nucleophile is low, a mixture of products may be obtained since allyl rearrangements may take place. > The reaction works best with primary unhindered allyl chlorides.

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Answer 1

Question

Chapter 11.2, Problem 6P

Interpretation Introduction

Interpretation:

A reason behind the betteryield of the substitution product of trans-1-chloro-2-butene than 3-chloro-1-butene is to be discussed.

Concept Introduction:
>
Allyl chlorides have a chlorine atom attached on the carbon atom adjacent to C=C
>
SN2 reactions of ally chlorides proceed mainly with substitution rather than elimination.
>
A good nucleophile exclusively forms the substitution product.When the concentration of nucleophile is low, a mixture of products may be obtained since allyl rearrangements may take place.
>
The reaction works best with primary unhindered allyl chlorides.

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Answer 2

Question

Chapter 11.2, Problem 6P

Interpretation Introduction

Interpretation:

A reason behind the betteryield of the substitution product of trans-1-chloro-2-butene than 3-chloro-1-butene is to be discussed.

Concept Introduction:
>
Allyl chlorides have a chlorine atom attached on the carbon atom adjacent to C=C
>
SN2 reactions of ally chlorides proceed mainly with substitution rather than elimination.
>
A good nucleophile exclusively forms the substitution product.When the concentration of nucleophile is low, a mixture of products may be obtained since allyl rearrangements may take place.
>
The reaction works best with primary unhindered allyl chlorides.

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Answer 3

Question

Chapter 11.2, Problem 6P

Interpretation Introduction

Interpretation:

A reason behind the betteryield of the substitution product of trans-1-chloro-2-butene than 3-chloro-1-butene is to be discussed.

Concept Introduction:
>
Allyl chlorides have a chlorine atom attached on the carbon atom adjacent to C=C
>
SN2 reactions of ally chlorides proceed mainly with substitution rather than elimination.
>
A good nucleophile exclusively forms the substitution product.When the concentration of nucleophile is low, a mixture of products may be obtained since allyl rearrangements may take place.
>
The reaction works best with primary unhindered allyl chlorides.

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Answer 4

Question

Chapter 11.2, Problem 6P

Interpretation Introduction

Interpretation:

A reason behind the betteryield of the substitution product of trans-1-chloro-2-butene than 3-chloro-1-butene is to be discussed.

Concept Introduction:
>
Allyl chlorides have a chlorine atom attached on the carbon atom adjacent to C=C
>
SN2 reactions of ally chlorides proceed mainly with substitution rather than elimination.
>
A good nucleophile exclusively forms the substitution product.When the concentration of nucleophile is low, a mixture of products may be obtained since allyl rearrangements may take place.
>
The reaction works best with primary unhindered allyl chlorides.

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Answer 5

Chapter 11.2, Problem 6P

Interpretation Introduction

Interpretation:

A reason behind the betteryield of the substitution product of trans-1-chloro-2-butene than 3-chloro-1-butene is to be discussed.

Concept Introduction:
>
Allyl chlorides have a chlorine atom attached on the carbon atom adjacent to C=C
>
SN2 reactions of ally chlorides proceed mainly with substitution rather than elimination.
>
A good nucleophile exclusively forms the substitution product.When the concentration of nucleophile is low, a mixture of products may be obtained since allyl rearrangements may take place.
>
The reaction works best with primary unhindered allyl chlorides.

Answer 6

Chapter 11.2, Problem 6P

Interpretation Introduction

Interpretation:

A reason behind the betteryield of the substitution product of trans-1-chloro-2-butene than 3-chloro-1-butene is to be discussed.

Concept Introduction:
>
Allyl chlorides have a chlorine atom attached on the carbon atom adjacent to C=C
>
SN2 reactions of ally chlorides proceed mainly with substitution rather than elimination.
>
A good nucleophile exclusively forms the substitution product.When the concentration of nucleophile is low, a mixture of products may be obtained since allyl rearrangements may take place.
>
The reaction works best with primary unhindered allyl chlorides.

Answer 7

Chapter 11.2, Problem 6P

Interpretation Introduction

Interpretation:

A reason behind the betteryield of the substitution product of trans-1-chloro-2-butene than 3-chloro-1-butene is to be discussed.

Concept Introduction:
>
Allyl chlorides have a chlorine atom attached on the carbon atom adjacent to C=C
>
SN2 reactions of ally chlorides proceed mainly with substitution rather than elimination.
>
A good nucleophile exclusively forms the substitution product.When the concentration of nucleophile is low, a mixture of products may be obtained since allyl rearrangements may take place.
>
The reaction works best with primary unhindered allyl chlorides.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11.1 - Prob. 1P Ch. 11.1 - Prob. 2P Ch. 11.2 - The two compounds shown differ by a factor of 60...Ch. 11.2 - Prob. 4P Ch. 11.2 - Prob. 5P Ch. 11.2 - Prob. 6P Ch. 11.3 - Prob. 7P Ch. 11.3 - Prob. 8P Ch. 11.3 - Evaluate 2,3,3-trimethyl-1-butene as a candidate...Ch. 11.4 - After heating a solution of allyl tert-butyl...

Solution Summary: The author compares the structure of trans-1-chloro-2-butene and Text3-

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