Chapter 11.2, Problem 11.3PSP

(a)

Interpretation Introduction

Interpretation:

The determination of complete rate law from the data is possible or not has to be examined.

Concept Introduction:

The relationship between rate and initial concentration of reactant is described by rate law.  It is an experimentally determined equation and cannot be found out theoretically from the stoichiometry of the reactants and products.

  $rate=k{\left[concentrationofthereac\tan t\right]}^m$

Where, $k$ is the rate constant and $m$ is the order of the reaction.

(b)

Interpretation Introduction

Interpretation:

The rate law has to be determined by assuming that the rate does not depend on the concentration of hydroxide ion.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Rate constant has to be calculated by assuming that the rate does not depend on the concentration of hydroxide ion.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The initial rate of the reaction has to be calculated.

Concept Introduction:

Refer to part (a).

(e)

Interpretation Introduction

Interpretation:

The rate of the reaction has to be calculated when the concentration of $C{v}^{+}$ is half the initial value of $0.00045M.$

Concept Introduction:

Refer to part (a).