The order of the reaction with respect to each reactant from the given rate law r a t e = k [ H C r O 4 − ] [ H 2 O 2 ] [ H + ] has to be determined.

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Answer 1

Question

Chapter 11, Problem 96QRT

(a)

Interpretation Introduction

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

(b)

Interpretation Introduction

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

(c)

Interpretation Introduction

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

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The rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.

Answer 2

Question

Chapter 11, Problem 96QRT

(a)

Interpretation Introduction

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

(b)

Interpretation Introduction

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

(c)

Interpretation Introduction

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

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Answer 3

Question

Chapter 11, Problem 96QRT

(a)

Interpretation Introduction

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

(b)

Interpretation Introduction

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

(c)

Interpretation Introduction

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Expert Solution & Answer

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Answer 4

Question

Chapter 11, Problem 96QRT

(a)

Interpretation Introduction

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

(b)

Interpretation Introduction

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

(c)

Interpretation Introduction

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Expert Solution & Answer

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Answer 5

Chapter 11, Problem 96QRT

(a)

Interpretation Introduction

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

(b)

Interpretation Introduction

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

(c)

Interpretation Introduction

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Answer 6

Chapter 11, Problem 96QRT

(a)

Interpretation Introduction

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

Answer 7

Chapter 11, Problem 96QRT

(a)

Interpretation Introduction

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

Answer 8

(b)

Interpretation Introduction

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Answer 9

(b)

Interpretation Introduction

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Answer 10

(c)

Interpretation Introduction

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Answer 11

(c)

Interpretation Introduction

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 11.1 - For the reaction of crystal violet with NaOH(aq),...Ch. 11.1 - (a) From data in Table 11.1, calculate the rate of...Ch. 11.1 - For the reaction 4NO2(g)+O2(g)2N2O5(g) (a) express...Ch. 11.1 - Instantaneous rates for the reaction of hydroxide...Ch. 11.1 - Prob. 11.3CE Ch. 11.2 - Prob. 11.4E Ch. 11.2 - Prob. 11.3PSP Ch. 11.2 - Prob. 11.5E Ch. 11.3 - Prob. 11.4PSP Ch. 11.3 - Prob. 11.5PSP

The order of the reaction with respect to each reactant from the given rate law r a t e = k [ H C r O 4 − ] [ H 2 O 2 ] [ H + ] has to be determined.

Solution Summary: The author explains that the order of the reaction with respect to each reactant from the given rate law ratekleft[HCrO_4-] is one.

Videos

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Want to see the full answer?

Chapter 11 Solutions

The order of the reaction with respect to each reactant from the given rate law r a t e = k [ H C r O 4 − ] [ H 2 O 2 ] [ H + ] has to be determined.

Solution Summary: The author explains that the order of the reaction with respect to each reactant from the given rate law ratekleft[HCrO_4-] is one.

Videos

Interpretation: The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

Interpretation: It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction. The mechanism for the reaction is given below. HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Interpretation: The rate-limiting step in the given mechanism has to be identified. The mechanism for the reaction is given below. HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

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Chapter 11 Solutions

Interpretation:

The order of the reaction with respect to each reactant from the given rate law rate = k[HCrO4−][H2O2][H+] has to be determined.

Interpretation:

It has to be shown that the steps for the given mechanism are consistent with the overall equation of the reaction.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O

Interpretation:

The rate-limiting step in the given mechanism has to be identified.

The mechanism for the reaction is given below.

HCrO4−+H+ ⇄H2CrO4H2CrO4+H2O2→H2CrO(O2)2+H2OH2CrO(O2)2 +H2O2 →CrO(O2)2+ 2 H2O