Chapter 11, Problem 59E

(a)

Interpretation Introduction

Interpretation: The rate law of the given elementary reactions is to be determined.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.

To determine: The rate law for the elementary reaction,

${\text{CH}}_{\text{3}}\text{NC}\left(g\right)\stackrel{}{\to }{\text{CH}}_{\text{3}}\text{CN}\left(g\right)$

(b)

Interpretation Introduction

Interpretation: The rate law of the given elementary reactions is to be determined.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.

To determine: The rate law for the elementary reaction,

${\text{O}}_{\text{3}}\left(g\right)+\text{NO}\left(g\right)\stackrel{}{\to }{\text{O}}_{\text{2}}\left(g\right){\text{+NO}}_{\text{2}}\left(g\right)$

(c)

Interpretation Introduction

Interpretation: The rate law of the given elementary reactions is to be determined.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.

To determine: The rate law for the elementary reaction,

${\text{O}}_{\text{3}}\left(g\right)\stackrel{}{\to }{\text{O}}_{\text{2}}\left(g\right)\text{+O}\left(g\right)$

(d)

Interpretation Introduction

Interpretation: The rate law of the given elementary reactions is to be determined.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.

To determine: The rate law for the elementary reaction,

${\text{O}}_{\text{3}}\left(g\right)+\text{O}\left(g\right)\stackrel{}{\to }{\text{2O}}_{\text{2}}\left(g\right)$