The rate law reaction of decomposition of NOBr and half-life is given. The rate constant for the given value of half life is to be calculated. Also, the time required for the given change in the concentration of NOBr is to be calculated. Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. To determine : The rate constant for 2 .00 s half life.
The rate law reaction of decomposition of NOBr and half-life is given. The rate constant for the given value of half life is to be calculated. Also, the time required for the given change in the concentration of NOBr is to be calculated. Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. To determine : The rate constant for 2 .00 s half life.
Solution Summary: The author explains the rate law reaction of decomposition of NOBr and half-life.
Definition Definition Study of the speed of chemical reactions and other factors that affect the rate of reaction. It also extends toward the mechanism involved in the reaction.
Chapter 11, Problem 54E
(a)
Interpretation Introduction
Interpretation: The rate law reaction of decomposition of
NOBr and half-life is given. The rate constant for the given value of half life is to be calculated. Also, the time required for the given change in the concentration of
NOBr is to be calculated.
Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.
To determine: The rate constant for
2.00s half life.
(b)
Interpretation Introduction
Interpretation: The rate law reaction of decomposition of
NOBr and half-life is given. The rate constant for the given value of half life is to be calculated. Also, the time required for the given change in the concentration of
NOBr is to be calculated.
Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.
To determine: The time taken by
0.900MNOBr to decrease to a concentration to
0.100M.
MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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