The expected products obtained from the given reaction have to be predicted. Concept introduction: Esterification reaction and intermolecular esterification reactions: Carboxylic acid and alcohol reacts to form an ester when the reaction proceeds under acidic condition. This type of reaction is known as esterification reaction . General scheme for esterification reaction: If the carboxylic acid and alcohol functional groups are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular esterification reaction. Example for intermolecular esterification reaction:

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Answer 1

Question

Chapter 11, Problem 51P

(a)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Esterification reaction and intermolecular esterification reactions:

Carboxylic acid and alcohol reacts to form an ester when the reaction proceeds under acidic condition. This type of reaction is known as esterification reaction.

General scheme for esterification reaction:

If the carboxylic acid and alcohol functional groups are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular esterification reaction.

Example for intermolecular esterification reaction:

(b)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Transesterification and intermolecular transesterification reactions:

In the presence of an acid, ester and alcohol forms another new ester which is known as transester and a new alcohol will also be formed. This type of reaction is called transesterification reaction.

General scheme for transesterification reaction:

If the ester and alcohol are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular transesterification reaction.

Example for intermolecular transesterification reaction:

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5. Please draw in the blanks the missing transition states and the correlated products. Explicitly display relevant absolute stereochemical configuration. MeOH I OMe H Endo transition state, dienophile approaching from the bottom of diene + H ཎྞཾ ཌཱརཱ༔,_o OMe H H OMe Endo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) + Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) MeO H H MeO H MeO H MeO H H

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Answer 2

Question

Chapter 11, Problem 51P

(a)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Esterification reaction and intermolecular esterification reactions:

Carboxylic acid and alcohol reacts to form an ester when the reaction proceeds under acidic condition. This type of reaction is known as esterification reaction.

General scheme for esterification reaction:

If the carboxylic acid and alcohol functional groups are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular esterification reaction.

Example for intermolecular esterification reaction:

(b)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Transesterification and intermolecular transesterification reactions:

In the presence of an acid, ester and alcohol forms another new ester which is known as transester and a new alcohol will also be formed. This type of reaction is called transesterification reaction.

General scheme for transesterification reaction:

If the ester and alcohol are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular transesterification reaction.

Example for intermolecular transesterification reaction:

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Answer 3

Question

Chapter 11, Problem 51P

(a)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Esterification reaction and intermolecular esterification reactions:

Carboxylic acid and alcohol reacts to form an ester when the reaction proceeds under acidic condition. This type of reaction is known as esterification reaction.

General scheme for esterification reaction:

If the carboxylic acid and alcohol functional groups are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular esterification reaction.

Example for intermolecular esterification reaction:

(b)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Transesterification and intermolecular transesterification reactions:

In the presence of an acid, ester and alcohol forms another new ester which is known as transester and a new alcohol will also be formed. This type of reaction is called transesterification reaction.

General scheme for transesterification reaction:

If the ester and alcohol are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular transesterification reaction.

Example for intermolecular transesterification reaction:

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Answer 4

Question

Chapter 11, Problem 51P

(a)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Esterification reaction and intermolecular esterification reactions:

Carboxylic acid and alcohol reacts to form an ester when the reaction proceeds under acidic condition. This type of reaction is known as esterification reaction.

General scheme for esterification reaction:

If the carboxylic acid and alcohol functional groups are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular esterification reaction.

Example for intermolecular esterification reaction:

(b)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Transesterification and intermolecular transesterification reactions:

In the presence of an acid, ester and alcohol forms another new ester which is known as transester and a new alcohol will also be formed. This type of reaction is called transesterification reaction.

General scheme for transesterification reaction:

If the ester and alcohol are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular transesterification reaction.

Example for intermolecular transesterification reaction:

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Answer 5

Chapter 11, Problem 51P

(a)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Esterification reaction and intermolecular esterification reactions:

Carboxylic acid and alcohol reacts to form an ester when the reaction proceeds under acidic condition. This type of reaction is known as esterification reaction.

General scheme for esterification reaction:

If the carboxylic acid and alcohol functional groups are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular esterification reaction.

Example for intermolecular esterification reaction:

(b)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Transesterification and intermolecular transesterification reactions:

In the presence of an acid, ester and alcohol forms another new ester which is known as transester and a new alcohol will also be formed. This type of reaction is called transesterification reaction.

General scheme for transesterification reaction:

If the ester and alcohol are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular transesterification reaction.

Example for intermolecular transesterification reaction:

Answer 6

Chapter 11, Problem 51P

(a)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Esterification reaction and intermolecular esterification reactions:

Carboxylic acid and alcohol reacts to form an ester when the reaction proceeds under acidic condition. This type of reaction is known as esterification reaction.

General scheme for esterification reaction:

If the carboxylic acid and alcohol functional groups are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular esterification reaction.

Example for intermolecular esterification reaction:

Answer 7

Chapter 11, Problem 51P

(a)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Esterification reaction and intermolecular esterification reactions:

Carboxylic acid and alcohol reacts to form an ester when the reaction proceeds under acidic condition. This type of reaction is known as esterification reaction.

General scheme for esterification reaction:

If the carboxylic acid and alcohol functional groups are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular esterification reaction.

Example for intermolecular esterification reaction:

Answer 8

(b)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Transesterification and intermolecular transesterification reactions:

In the presence of an acid, ester and alcohol forms another new ester which is known as transester and a new alcohol will also be formed. This type of reaction is called transesterification reaction.

General scheme for transesterification reaction:

If the ester and alcohol are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular transesterification reaction.

Example for intermolecular transesterification reaction:

Answer 9

(b)

Interpretation Introduction

Interpretation:

The expected products obtained from the given reaction have to be predicted.

Concept introduction:

Transesterification and intermolecular transesterification reactions:

In the presence of an acid, ester and alcohol forms another new ester which is known as transester and a new alcohol will also be formed. This type of reaction is called transesterification reaction.

General scheme for transesterification reaction:

If the ester and alcohol are present within the same compound, then cyclic ester is formed which is known as lactone and the reaction is known as intermolecular transesterification reaction.

Example for intermolecular transesterification reaction:

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11.1 - The aromas of many flowers and fruits are due to...Ch. 11.1 - Name the following compounds:Ch. 11.1 - Prob. 3P Ch. 11.2 - Prob. 4P Ch. 11.2 - Prob. 5P Ch. 11.4 - a. What is the product of the reaction of acetyl...Ch. 11.4 - Prob. 7P Ch. 11.5 - Using the pKa values listed in Table 11.1, predict...Ch. 11.6 - Starting with acetyl chloride, what neutral...Ch. 11.6 - Prob. 10P

Solution Summary: The author describes the esterification reaction and intermolecular esterification reactions. Carboxylic acid and alcohol react to form a transester when the reaction proceeds under acidic conditions.

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Chapter 11 Solutions