EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Question
Chapter 11, Problem 43P
Interpretation Introduction
Interpretation:
The maximum yield of 2-pentene for the reaction given below has to be determined
Concept introduction:
Organolithium compound:
OrganoCuprate:
A dialkyl lithium cuprate used to replace a halogen in an alkyl, aryl or vinyl halide with an alkyl group.
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H8.
Please help me check if the information below is correct for both the types of reactions and the special rules or laws to predict predominant products for alcohols. If not please insert the correct information. Please make the information in jot notes.
TYPES OF REACTIONS ALCOHOL:
Dehydration: This is a reaction where an alcohol loses a water molecule to form an alkene. For example, when ethanol is treated with an acidic catalyst, such as sulfuric acid, it undergoes dehydration to form ethene (CH2=CH2) and water.
Oxidation: In this reaction, an alcohol is converted to either a carbonyl compound or a carboxylic acid. For example, primary alcohols can be oxidized to aldehydes or carboxylic acids, while secondary alcohols can be oxidized to ketones. Tertiary alcohols are not oxidized under normal conditions.
Esterification: This reaction involves the formation of an ester from an alcohol and a carboxylic acid in the presence of an acid catalyst. For example, when ethanol is…
Use the following reagent table for the reaction of :
cyclohexanol + H2 SO4 → cyclohexene
Chemical
MW (g/mol) Density (g/mL) mmols used
Amount used
cyclohexanol
100.16
0.9624
1.50 mL
Sulfuric Acid
98.08
1.83
1.00 mL
cyclohexene
82.14
Using the information from the previous questions, if 0.95 g of cyclohexene were
formed during the reaction, determine the % yield. Answer with 2 decimal places.
Chapter 11 Solutions
EBK ORGANIC CHEMISTRY
Ch. 11.1 - Prob. 1PCh. 11.2 - Which is more reactive an organolithium compound...Ch. 11.2 - Prob. 3PCh. 11.3 - Muscalure is the sex attractant of the common...Ch. 11.3 - Prob. 7PCh. 11.3 - Prob. 8PCh. 11.3 - Prob. 9PCh. 11.3 - Prob. 10PCh. 11.4 - Prob. 13PCh. 11.4 - Prob. 14P
Ch. 11.4 - Prob. 15PCh. 11.4 - Prob. 16PCh. 11.4 - Prob. 17PCh. 11.4 - Prob. 19PCh. 11.4 - Show how the Suzuki and/or Heck reactions can be...Ch. 11.4 - Identify two pairs of an alkyl bromide and an...Ch. 11.5 - Prob. 22PCh. 11.5 - Draw the product of ring-closing metathesis for...Ch. 11.5 - Prob. 25PCh. 11.5 - Prob. 26PCh. 11 - Prob. 27PCh. 11 - Prob. 28PCh. 11 - The coupling of an alkyne with an aryl halide in...Ch. 11 - Identify A through H.Ch. 11 - Using the given starting material, any necessary...Ch. 11 - What alkyl halide reacts with lithium...Ch. 11 - Prob. 33PCh. 11 - Prob. 34PCh. 11 - The following compound undergoes an intramolecular...Ch. 11 - Using ethynyleyclohexane as a starting material...Ch. 11 - Prob. 37PCh. 11 - Using the given starting material, any necessary...Ch. 11 - Prob. 39PCh. 11 - A student added an equivalent of...Ch. 11 - Using the given starting material, any necessary...Ch. 11 - Prob. 42PCh. 11 - Prob. 43PCh. 11 - Bombykol is the sex pheromone of the silk moth....Ch. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - A dibromide loses only one bromine when it reacts...Ch. 11 - What starting material is required in order to...Ch. 11 - What product is obtained from ring-opening...
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Similar questions
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