EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Question
Chapter 11.2, Problem 3P
Interpretation Introduction
Interpretation:
The
Concept introduction:
- Organometallic compound it can be defined as the compound which contain Carbon – Metal bond.
- The carbon attached to the halogen in an
alkyl halide is an electrophile, whereas the carbon attached to the metal in an organometallic compound is a nucleophile. - Transmetallation:
Transmetallation occurs when an organometallic compound is added to a metal halid whose metal is more electronegative (closer to the electronegative of carbon) than the metal in the organometallic compound.
- Grignard reagent:
The compound that results when magnesium is inserted between the carbon atom and the halogen of an alkyl halide like
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1. Write down the unique reactions in organometallic chemistry with suitable examples.
2. Why co-ordination compounds became more colorful in solution form then normal organic compounds.
b) i) Draw the different structural isomers of the 6-membered ring compound
[GAAIBNPAS]H6 in which there are alternating Group 13 and 15 elements.
ii) The isomers containing both B-N and AI-N bonding are the most stable.
Explain why this is the case.
ii) How would you expect the structure and reactivity of the heterocycles
[GAAIBNPAS]H6 to compare with borazine?
iv) While borazine exists as a planar ring compound, the [GAAIBNPAS]H6 ring
compounds dimerize. Explain these observations.
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Question 7
Chapter 11 Solutions
EBK ORGANIC CHEMISTRY
Ch. 11.1 - Prob. 1PCh. 11.2 - Which is more reactive an organolithium compound...Ch. 11.2 - Prob. 3PCh. 11.3 - Muscalure is the sex attractant of the common...Ch. 11.3 - Prob. 7PCh. 11.3 - Prob. 8PCh. 11.3 - Prob. 9PCh. 11.3 - Prob. 10PCh. 11.4 - Prob. 13PCh. 11.4 - Prob. 14P
Ch. 11.4 - Prob. 15PCh. 11.4 - Prob. 16PCh. 11.4 - Prob. 17PCh. 11.4 - Prob. 19PCh. 11.4 - Show how the Suzuki and/or Heck reactions can be...Ch. 11.4 - Identify two pairs of an alkyl bromide and an...Ch. 11.5 - Prob. 22PCh. 11.5 - Draw the product of ring-closing metathesis for...Ch. 11.5 - Prob. 25PCh. 11.5 - Prob. 26PCh. 11 - Prob. 27PCh. 11 - Prob. 28PCh. 11 - The coupling of an alkyne with an aryl halide in...Ch. 11 - Identify A through H.Ch. 11 - Using the given starting material, any necessary...Ch. 11 - What alkyl halide reacts with lithium...Ch. 11 - Prob. 33PCh. 11 - Prob. 34PCh. 11 - The following compound undergoes an intramolecular...Ch. 11 - Using ethynyleyclohexane as a starting material...Ch. 11 - Prob. 37PCh. 11 - Using the given starting material, any necessary...Ch. 11 - Prob. 39PCh. 11 - A student added an equivalent of...Ch. 11 - Using the given starting material, any necessary...Ch. 11 - Prob. 42PCh. 11 - Prob. 43PCh. 11 - Bombykol is the sex pheromone of the silk moth....Ch. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - A dibromide loses only one bromine when it reacts...Ch. 11 - What starting material is required in order to...Ch. 11 - What product is obtained from ring-opening...
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