EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Chapter 11.2, Problem 3P
Interpretation Introduction

Interpretation:

The organometallic compound formed by excess reaction of methylmagnesium chloride with GaCl3.

Concept introduction:

  • Organometallic compound it can be defined as the compound which contain Carbon – Metal bond.
  • The carbon attached to the halogen in an alkyl halide is an electrophile, whereas the carbon attached to the metal in an organometallic compound is a nucleophile.
  • Transmetallation:

Transmetallation occurs when an organometallic compound is added to a metal halid whose metal is more electronegative (closer to the electronegative of carbon) than the metal in the organometallic compound.

  • Grignard reagent:

The compound that results when magnesium is inserted between the carbon atom and the halogen of an alkyl halide like RMgBr & RMgCl  is known as Grignard reagent.  They are also known as Organomagnesium compounds.

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1. Write down the unique reactions in organometallic chemistry with suitable examples. 2. Why co-ordination compounds became more colorful in solution form then normal organic compounds. ​​​​
b) i) Draw the different structural isomers of the 6-membered ring compound [GAAIBNPAS]H6 in which there are alternating Group 13 and 15 elements. ii) The isomers containing both B-N and AI-N bonding are the most stable. Explain why this is the case. ii) How would you expect the structure and reactivity of the heterocycles [GAAIBNPAS]H6 to compare with borazine? iv) While borazine exists as a planar ring compound, the [GAAIBNPAS]H6 ring compounds dimerize. Explain these observations. H -ЕН -E H-E НЕ ЕН E НЕ- ЕН H `E H. H É-H НЕ E = Heteroatom エー山、 w-I
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Chapter 11 Solutions

EBK ORGANIC CHEMISTRY

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