Chemistry In Focus
6th Edition
ISBN: 9781305084476
Author: Tro, Nivaldo J., Neu, Don.
Publisher: Cengage Learning
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Chapter 11, Problem 43E
Jet airplanes often fly in the lower stratosphere, where the pressure drops to approximately 245 mm Hg. In her suitcase, a passenger packed a sealed, crumpled plastic bag with an initial volume of 0.35 L. If the baggage compartment is not pressurized, what is the volume of the plastic bag at altitude?
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19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
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functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
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(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
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3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
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acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
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LiBr
LiI
LiF
LiCl
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
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Chapter 11 Solutions
Chemistry In Focus
Ch. 11 - Prob. 11.1YTCh. 11 - A balloon has an initial temperature of 30.0C and...Ch. 11 - Prob. 11.3YTCh. 11 - Prob. 1SCCh. 11 - Prob. 2SCCh. 11 - Prob. 3SCCh. 11 - Prob. 4SCCh. 11 - Prob. 1ECh. 11 - Prob. 2ECh. 11 - Prob. 3E
Ch. 11 - Prob. 4ECh. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Why is oxygen central to the existence of animal...Ch. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - Prob. 19ECh. 11 - What are the adverse health and environmental...Ch. 11 - Prob. 21ECh. 11 - Prob. 22ECh. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - With the help of chemical equations, explain how...Ch. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Why does ozone deplete severely over Antarctica...Ch. 11 - Has ozone been depleted over other areas of the...Ch. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 - The pressure on Mt. Everest is approximately 0.31...Ch. 11 - Prob. 38ECh. 11 - Prob. 39ECh. 11 - The pressure in Denver, Colorado, is approximately...Ch. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Jet airplanes often fly in the lower stratosphere,...Ch. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - A 2.8 L balloon is warmed over a toaster, and its...Ch. 11 - A cylinder with a movable piston has an initial...Ch. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - Prob. 53ECh. 11 - Prob. 54ECh. 11 - Explain the difference between the effects of...Ch. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60E
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