The following pairs have to be ranked in order of increasing boiling point. Concept Introduction: Vapor pressure is nothing but the pressure of a vapor in contact with its liquid or solid form. When a liquid and vapor are in equilibrium the pressure exerted by the vapor is called the equilibrium vapor pressure. Intermolecular force: The attractive force that withholds two molecules is called as intermolecular force. The influence of intermolecular forces depends on molar mass and the functional group present in the molecule. If intermolecular force is small the vapor pressure of the substance is high and the boiling point will be low. The boiling point of a liquid is the temperature at which its vapor pressure is equal to the external pressure.

Question

Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

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Chapter 11, Problem 36GQ

Interpretation Introduction

Interpretation: The following pairs have to be ranked in order of increasing boiling point.

Concept Introduction: Vapor pressure is nothing but the pressure of a vapor in contact with its liquid or solid form.

When a liquid and vapor are in equilibrium the pressure exerted by the vapor is called the equilibrium vapor pressure.

Intermolecular force: The attractive force that withholds two molecules is called as intermolecular force. The influence of intermolecular forces depends on molar mass and the functional group present in the molecule.

If intermolecular force is small the vapor pressure of the substance is high and the boiling point will be low.

The boiling point of a liquid is the temperature at which its vapor pressure is equal to the external pressure.

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

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