The compound having the higher boiling point has to be identified. Concept Introduction: Boiling point: It is the temperature at which liquid converts to vapor. At boiling point the vapor pressure of liquid and the pressure of the surroundings are equal. The boiling point of a liquid increases as the intermolecular forces within the compound increases.
The compound having the higher boiling point has to be identified. Concept Introduction: Boiling point: It is the temperature at which liquid converts to vapor. At boiling point the vapor pressure of liquid and the pressure of the surroundings are equal. The boiling point of a liquid increases as the intermolecular forces within the compound increases.
Solution Summary: The author explains that the compound having the higher boiling point has to be identified.
Interpretation: The compound having the higher boiling point has to be identified.
Concept Introduction:
Boiling point: It is the temperature at which liquid converts to vapor. At boiling point the vapor pressure of liquid and the pressure of the surroundings are equal.
The boiling point of a liquid increases as the intermolecular forces within the compound increases.
(b)
Interpretation Introduction
Interpretation: The compound having the higher boiling point has to be identified.
Concept Introduction:
Boiling point: It is the temperature at which liquid converts to vapor. At boiling point the vapor pressure of liquid and the pressure of the surroundings are equal.
The boiling point of a liquid increases as the intermolecular forces within the compound increases.
(c)
Interpretation Introduction
Interpretation: The compound having the higher boiling point has to be identified.
Concept Introduction:
Boiling point: It is the temperature at which liquid converts to vapor. At boiling point the vapor pressure of liquid and the pressure of the surroundings are equal.
The boiling point of a liquid increases as the intermolecular forces within the compound increases.
Protecting Groups and Carbonyls
6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet
shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to
generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation,
reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.)
III + VI
HS
HS
H+
CH,CH,Li
III
I
II
IV
CI + P(Ph)3
V
༼
Hint: no strong base added
VI
S
VII
IX
HO
VIII
-MgBr
HgCl2,HgO
HO.
isomerization
aqeuous solution
H,SO,
༽༽༤༽༽
X
MeOH
Hint: enhances selectivity for reaction at the S
X
☑
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