Introductory Chemistry: Foundation - Text (Looseleaf)
9th Edition
ISBN: 9781337399623
Author: ZUMDAHL
Publisher: Cengage
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Textbook Question
Chapter 11, Problem 28QAP
Section 11.6 uses a "firefly" analogy to illustrate how the wave mechanical modal for the atom differs from Bohr’s. model. Explain this analogy.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 11 Solutions
Introductory Chemistry: Foundation - Text (Looseleaf)
Ch. 11.4 - now have evidence that electron energy levels in...Ch. 11.8 - Prob. 11.1SCCh. 11.9 - Prob. 11.2SCCh. 11.10 - Prob. 11.3SCCh. 11.10 - Prob. 1CTCh. 11 - ow does probability ?t into the description of the...Ch. 11 - Prob. 2ALQCh. 11 - Prob. 3ALQCh. 11 - onsider the following statements: “The ionization...Ch. 11 - n going across a row of the periodic table,...
Ch. 11 - Prob. 6ALQCh. 11 - rue or false? The hydrogen atom has a 3 orbital....Ch. 11 - Prob. 8ALQCh. 11 - ake sense of the fact that metals tend to lose...Ch. 11 - Show how using the periodic table helps you find...Ch. 11 - r Questions 11—13, you will need to consider...Ch. 11 - Prob. 12ALQCh. 11 - Prob. 13ALQCh. 11 - Prob. 14ALQCh. 11 - Prob. 15ALQCh. 11 - What evidence do we have that energy levels in an...Ch. 11 - Explain the hydrogen emission spectrum. Why is it...Ch. 11 - There am an infinite number of allowed transitions...Ch. 11 - You have learned that each orbital is allowed two...Ch. 11 - Atom A has valence electrons that are lower in...Ch. 11 - Prob. 21ALQCh. 11 - Prob. 1QAPCh. 11 - hat questions were left unanswered by Rutherford’s...Ch. 11 - Prob. 3QAPCh. 11 - Prob. 4QAPCh. 11 - Prob. 5QAPCh. 11 - Prob. 6QAPCh. 11 - he “Chemistry in Focus" segment Light as a Sex...Ch. 11 - Prob. 8QAPCh. 11 - hen lithium salts are heated in a flame, they emit...Ch. 11 - The energy of a photon of visible light emitted by...Ch. 11 - Prob. 11QAPCh. 11 - An excited atom can release some or all of its...Ch. 11 - How is the energy carried per photon of light...Ch. 11 - When an atom energy from outside, the atom goes...Ch. 11 - Describe briefly why the study of electromagnetic...Ch. 11 - What does it mean to say that the hydrogen atom...Ch. 11 - Because a given element’s atoms emit only certain...Ch. 11 - How does the energy possessed by an emitted photon...Ch. 11 - Prob. 19QAPCh. 11 - When a tube containing hydrogen atoms is energized...Ch. 11 - What are the essential points of Bohr‘s theory of...Ch. 11 - According to Bohr, what happens to the electron...Ch. 11 - How does the Bohr theory account for the observed...Ch. 11 - Why was Bohr's theory for the hydrogen atom...Ch. 11 - What major assumption (that was analogous to what...Ch. 11 - Discuss briefly the difference between an orbit...Ch. 11 - Discuss briefly the difference between an orbit...Ch. 11 - Section 11.6 uses a "firefly" analogy to...Ch. 11 - Your text describes the probability map for an s...Ch. 11 - Consider the following representation of a set of...Ch. 11 - What are the differences between the :math>2s...Ch. 11 - What overall shape do the 2p and 3p orbitals have?...Ch. 11 - Prob. 33QAPCh. 11 - When the electron in hydrogen is in the n=3...Ch. 11 - Although a hydrogen atom has only one electron,...Ch. 11 - Complete the following table. trong>Value of n...Ch. 11 - When describing the electrons in an orbital, we...Ch. 11 - Why can only two electrons occupy a particular...Ch. 11 - How does the energy of a principal energy level...Ch. 11 - The number of sublevels in a principal energy...Ch. 11 - According to the Pauli exclusion principle, a...Ch. 11 - Prob. 42QAPCh. 11 - Which of the following orbital designations...Ch. 11 - Which of the following orbital designations is...Ch. 11 - Which orbital is the first be filled in any atom?...Ch. 11 - When a hydrogen atom is in its ground state, in...Ch. 11 - Prob. 47QAPCh. 11 - How are the electron arrangements in a given group...Ch. 11 - Write the full electron configuration ( 1s22s2...Ch. 11 - To which element does each of the following...Ch. 11 - Write the full electron configuration...Ch. 11 - To which element does each of the following...Ch. 11 - Write the complete orbital diagram for each of the...Ch. 11 - Prob. 54QAPCh. 11 - Prob. 55QAPCh. 11 - For each of the following, give an atom and its...Ch. 11 - Why do we believe that the valence electrons of...Ch. 11 - Would you expect the Valence electrons of rubidium...Ch. 11 - Using the symbol of the previous noble gas in...Ch. 11 - Prob. 60QAPCh. 11 - Prob. 61QAPCh. 11 - How many valence electrons does each of the...Ch. 11 - How many 3d electrons are found in each of the...Ch. 11 - Based on the elements’ locations on the periodic...Ch. 11 - For each of the following elements, indicate which...Ch. 11 - Write the valence-electron configuration of each...Ch. 11 - Prob. 67QAPCh. 11 - The “Chemistry in Focus" segment The Chemistry of...Ch. 11 - What are some of the physical properties that...Ch. 11 - Prob. 70QAPCh. 11 - Give some similarities than exist among the...Ch. 11 - Give some similarities that exist among the...Ch. 11 - Which of the following elements most easily gives...Ch. 11 - Which elements in a given period (horizontal row)...Ch. 11 - Where are the most nonmetallic elements located on...Ch. 11 - Why do the metallic elements of a given period...Ch. 11 - Prob. 77QAPCh. 11 - The “Chemistry in Focus" segment Fireworks...Ch. 11 - Prob. 79QAPCh. 11 - In each of the following sets of elements, which...Ch. 11 - Arrange the following sets of elements in order of...Ch. 11 - In each of the following sets of elements,...Ch. 11 - Consider the bright line spectrum of hydrogen...Ch. 11 - Prob. 84APCh. 11 - The portion of the electromagnetic spectrum...Ch. 11 - A beam of light can be thought of as consisting of...Ch. 11 - Prob. 87APCh. 11 - The Energy levels of hydrogen (and other atoms)...Ch. 11 - According to Bohr, the electron in the hydrogen...Ch. 11 - Which of the following statements is false...Ch. 11 - Electrons found in the outemost principal energy...Ch. 11 - An unknown element is a nonmetal and has a...Ch. 11 - Prob. 93APCh. 11 - The current model of the atom in which essentially...Ch. 11 - Prob. 95APCh. 11 - Prob. 96APCh. 11 - Without referring to your textbook or a periodic...Ch. 11 - Prob. 98APCh. 11 - Prob. 99APCh. 11 - Prob. 100APCh. 11 - ight waves move through space at a speed of ters...Ch. 11 - Prob. 102APCh. 11 - ow does the attractive force that the nucleus...Ch. 11 - Prob. 104APCh. 11 - ased on the ground-state electron configuration of...Ch. 11 - lement X, which has a valence shell configuration...Ch. 11 - hy do we believe that the three electrons in the...Ch. 11 - Prob. 108APCh. 11 - Prob. 109APCh. 11 - Prob. 110APCh. 11 - Prob. 111APCh. 11 - ank the following elements in order of increasing...Ch. 11 - Prob. 113APCh. 11 - Prob. 114APCh. 11 - Prob. 115APCh. 11 - Prob. 116APCh. 11 - n each of the following sets of elements, indicate...Ch. 11 - Prob. 118APCh. 11 - Determine the maximum number of electrons that can...Ch. 11 - hich of the following statements is(are) true? The...Ch. 11 - ive the electron configurations for the following...Ch. 11 - Prob. 122CPCh. 11 - Prob. 123CPCh. 11 - Prob. 124CPCh. 11 - Prob. 125CPCh. 11 - Prob. 126CP
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