The rate of the given reaction has to be expressed in terms of Δ [ N 2 O 2 ] . Concept Introduction: Rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the reciprocal of the corresponding stoichiometric co-efficient to that. When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given. But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.

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Answer 1

Question

Chapter 11, Problem 17QRT

(a)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2O2].

Concept Introduction:

Rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the reciprocal of the corresponding stoichiometric co-efficient to that.

When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given.

But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.

(b)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PH

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PROPOSE REACTION MECHANISM FOR ACID-CATALYZED REACTION OF 3-PENTANONE WITH DIMETHYLAMINE

Answer 2

Question

Chapter 11, Problem 17QRT

(a)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2O2].

Concept Introduction:

Rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the reciprocal of the corresponding stoichiometric co-efficient to that.

When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given.

But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.

(b)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 11, Problem 17QRT

(a)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2O2].

Concept Introduction:

Rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the reciprocal of the corresponding stoichiometric co-efficient to that.

When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given.

But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.

(b)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 11, Problem 17QRT

(a)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2O2].

Concept Introduction:

Rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the reciprocal of the corresponding stoichiometric co-efficient to that.

When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given.

But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.

(b)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 11, Problem 17QRT

(a)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2O2].

Concept Introduction:

Rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the reciprocal of the corresponding stoichiometric co-efficient to that.

When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given.

But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.

(b)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 11, Problem 17QRT

(a)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2O2].

Concept Introduction:

Rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the reciprocal of the corresponding stoichiometric co-efficient to that.

When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given.

But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.

Answer 7

Chapter 11, Problem 17QRT

(a)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2O2].

Concept Introduction:

Rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the reciprocal of the corresponding stoichiometric co-efficient to that.

When the rate is expressed in terms of change in reactant concentration, a minus sign has to be given. Since change in time will be a positive quantity and reactant concentration decreases with time change in concentration of reactant will be negative. So in order to make the rate a positive quantity negative sign is given.

But if the rate is expressed in terms of change in concentration of products, which is a positive quantity, no need of negative sign in the rate expression.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11.1 - For the reaction of crystal violet with NaOH(aq),...Ch. 11.1 - (a) From data in Table 11.1, calculate the rate of...Ch. 11.1 - For the reaction 4NO2(g)+O2(g)2N2O5(g) (a) express...Ch. 11.1 - Instantaneous rates for the reaction of hydroxide...Ch. 11.1 - Prob. 11.3CE Ch. 11.2 - Prob. 11.4E Ch. 11.2 - Prob. 11.3PSP Ch. 11.2 - Prob. 11.5E Ch. 11.3 - Prob. 11.4PSP Ch. 11.3 - Prob. 11.5PSP

Solution Summary: The author explains that the rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the corresponding stoichiometric co-efficient to that.

Videos

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).

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Chapter 11 Solutions

Solution Summary: The author explains that the rate of the reaction can be expressed in terms of change in concentration of reactant and products by multiplying the corresponding stoichiometric co-efficient to that.

Videos

Interpretation: The rate of the given reaction has to be expressed in terms of Δ[N2]. Concept Introduction: Refer to part (a).

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Chapter 11 Solutions

Interpretation:

The rate of the given reaction has to be expressed in terms of Δ[N2].

Concept Introduction:

Refer to part (a).