Whether a linear and nonpolar molecule like CO 2 have a Raman spectrum or not has to be predicted. Concept introduction: The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are infrared or Raman active. If a molecule has center of symmetry, then the modes which are infrared -active will be Raman inactive and the modes that are infrared-inactive will be Raman active. The total number of vibrational degrees of freedom for the nonlinear molecule is represented by 3 N − 6 .

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Answer 1

Question

Chapter 11, Problem 11D.3DQ

Interpretation Introduction

Interpretation:

Whether a linear and nonpolar molecule like CO2 have a Raman spectrum or not has to be predicted.

Concept introduction:

The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are infrared or Raman active. If a molecule has center of symmetry, then the modes which are infrared -active will be Raman inactive and the modes that are infrared-inactive will be Raman active. The total number of vibrational degrees of freedom for the nonlinear molecule is represented by 3N−6.

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CS2(g) →CS(g) + S(g) The rate law is Rate = k[CS2] where k = 1.6 × 10−6 s−¹. S What is the concentration of CS2 after 5 hours if the initial concentration is 0.25 M?

CS2(g) → CS(g) + S(g) The rate law is Rate = k [CS2] where k = 1.6 × 10-6 s−1. S Calculate the half-life.

Answer 2

Question

Chapter 11, Problem 11D.3DQ

Interpretation Introduction

Interpretation:

Whether a linear and nonpolar molecule like CO2 have a Raman spectrum or not has to be predicted.

Concept introduction:

The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are infrared or Raman active. If a molecule has center of symmetry, then the modes which are infrared -active will be Raman inactive and the modes that are infrared-inactive will be Raman active. The total number of vibrational degrees of freedom for the nonlinear molecule is represented by 3N−6.

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Answer 3

Question

Chapter 11, Problem 11D.3DQ

Interpretation Introduction

Interpretation:

Whether a linear and nonpolar molecule like CO2 have a Raman spectrum or not has to be predicted.

Concept introduction:

The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are infrared or Raman active. If a molecule has center of symmetry, then the modes which are infrared -active will be Raman inactive and the modes that are infrared-inactive will be Raman active. The total number of vibrational degrees of freedom for the nonlinear molecule is represented by 3N−6.

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Answer 4

Question

Chapter 11, Problem 11D.3DQ

Interpretation Introduction

Interpretation:

Whether a linear and nonpolar molecule like CO2 have a Raman spectrum or not has to be predicted.

Concept introduction:

The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are infrared or Raman active. If a molecule has center of symmetry, then the modes which are infrared -active will be Raman inactive and the modes that are infrared-inactive will be Raman active. The total number of vibrational degrees of freedom for the nonlinear molecule is represented by 3N−6.

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Answer 5

Chapter 11, Problem 11D.3DQ

Interpretation Introduction

Interpretation:

Whether a linear and nonpolar molecule like CO2 have a Raman spectrum or not has to be predicted.

Concept introduction:

The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are infrared or Raman active. If a molecule has center of symmetry, then the modes which are infrared -active will be Raman inactive and the modes that are infrared-inactive will be Raman active. The total number of vibrational degrees of freedom for the nonlinear molecule is represented by 3N−6.

Answer 6

Chapter 11, Problem 11D.3DQ

Interpretation Introduction

Interpretation:

Whether a linear and nonpolar molecule like CO2 have a Raman spectrum or not has to be predicted.

Concept introduction:

The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are infrared or Raman active. If a molecule has center of symmetry, then the modes which are infrared -active will be Raman inactive and the modes that are infrared-inactive will be Raman active. The total number of vibrational degrees of freedom for the nonlinear molecule is represented by 3N−6.

Answer 7

Chapter 11, Problem 11D.3DQ

Interpretation Introduction

Interpretation:

Whether a linear and nonpolar molecule like CO2 have a Raman spectrum or not has to be predicted.

Concept introduction:

The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are infrared or Raman active. If a molecule has center of symmetry, then the modes which are infrared -active will be Raman inactive and the modes that are infrared-inactive will be Raman active. The total number of vibrational degrees of freedom for the nonlinear molecule is represented by 3N−6.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11 - Prob. 11A.1ST Ch. 11 - Prob. 11A.2ST Ch. 11 - Prob. 11B.1ST Ch. 11 - Prob. 11B.2ST Ch. 11 - Prob. 11B.3ST Ch. 11 - Prob. 11B.4ST Ch. 11 - Prob. 11C.1ST Ch. 11 - Prob. 11C.2ST Ch. 11 - Prob. 11D.1ST Ch. 11 - Prob. 11E.1ST

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Chapter 11 Solutions