The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified. Concept Introduction: Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms. Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms. Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

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Answer 1

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Answer 2

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

Answer 7

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

Solution Summary: The author explains that 1-chlorohexane and 2-butene are structural isomers with the same molecular formula but different spatial arrangement of atoms.

Concept explainers

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Chapter 11 Solutions

Solution Summary: The author explains that 1-chlorohexane and 2-butene are structural isomers with the same molecular formula but different spatial arrangement of atoms.

Concept explainers

Interpretation: The isomeric relationship between 1-butene and 2-butene has to be identified. Concept Introduction: Refer to part (a).

Interpretation: The isomeric relationship between 1,2-dichloroethene has to be identified. Concept Introduction: Refer to part (a).

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Chapter 11 Solutions

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).