The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified. Concept Introduction: Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms. Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms. Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

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Answer 1

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Propose a synthesis pathway for the following transformations. b) c) d)

Answer 2

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

Answer 7

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

Solution Summary: The author explains that 1-chlorohexane and 2-butene are structural isomers with the same molecular formula but different spatial arrangement of atoms.

Concept explainers

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Chapter 11 Solutions

Solution Summary: The author explains that 1-chlorohexane and 2-butene are structural isomers with the same molecular formula but different spatial arrangement of atoms.

Concept explainers

Interpretation: The isomeric relationship between 1-butene and 2-butene has to be identified. Concept Introduction: Refer to part (a).

Interpretation: The isomeric relationship between 1,2-dichloroethene has to be identified. Concept Introduction: Refer to part (a).

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Chapter 11 Solutions

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).