EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Textbook Question
Chapter 11, Problem 11.91CP
THC is the active component in marijuana (Section 11.5), and ethanol
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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label
each compound as chiral or achiral.
OH
HO
CI
Br
H
CI
CI
Br
CI
CI
Xf x f g
Br
D
OH
Br
Br
H₂N
R.
IN
Ill
I
-N
S
OMe
D
II
H
CO₂H
1/111
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These are synthesis questions. You need to show how the starting material can be converted into
the product(s) shown. You may use any reactions we have learned. Show all the reagents you
need. Show each molecule synthesized along the way and be sure to pay attention to the
regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made
along the way, you need to draw both enantiomers and label the mixture as "racemic".
All of the carbon atoms of the products must come from the starting material!
?
H
H
Q5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show
stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship
between each pair of the stereoisomers you have drawn.
Chapter 11 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 11.1 - Prob. 11.1PCh. 11.2 - Fill in all H's and lone pairs in each compound.Ch. 11.3 - Prob. 11.3PCh. 11.3 - Prob. 11.4PCh. 11.3 - Prob. 11.5PCh. 11.3 - Prob. 11.6PCh. 11.3 - How many lone pairs are present in lidocaine, the...Ch. 11.4 - Convert each compound to a condensed formula.Ch. 11.4 - Convert each condensed formula to a complete...Ch. 11.4 - Convert each skeletal structure to a complete...
Ch. 11.4 - How many H’s are bonded to each indicated carbon...Ch. 11.5 - Prob. 11.12PCh. 11.5 - For each compound: [1] Identify the functional...Ch. 11.5 - Prob. 11.14PCh. 11.5 - Prob. 11.15PCh. 11.5 - Prob. 11.16PCh. 11.5 - Identify all of the functional groups in atenolol,...Ch. 11.5 - Prob. 11.18PCh. 11.5 - Prob. 11.19PCh. 11.6 - Indicate the polar bonds in each compound. Label...Ch. 11.6 - Prob. 11.21PCh. 11.6 - Prob. 11.22PCh. 11.6 - Predict the water solubility of each compound....Ch. 11.6 - Prob. 11.24PCh. 11.7 - Prob. 11.25PCh. 11.7 - Prob. 11.26PCh. 11 - Prob. 11.27PCh. 11 - Prob. 11.28PCh. 11 - Complete each structure by filling in all H’s and...Ch. 11 - Prob. 11.30PCh. 11 - Prob. 11.31PCh. 11 - Prob. 11.32PCh. 11 - Prob. 11.33PCh. 11 - Prob. 11.34PCh. 11 - “Ecstasy” is a widely used illegal stimulant....Ch. 11 - Prob. 11.36PCh. 11 - Explain why each C—C—C bond angle in benzene...Ch. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - Prob. 11.40PCh. 11 - Convert each compound to a skeletal structure.Ch. 11 - Convert each compound to a skeletal structure.Ch. 11 - Convert each shorthand structure to a complete...Ch. 11 - Convert each shorthand structure to a complete...Ch. 11 - A and B are ball-and-stick models of two compounds...Ch. 11 - Prob. 11.46PCh. 11 - What is wrong in each of the following shorthand...Ch. 11 - Prob. 11.48PCh. 11 - Prob. 11.49PCh. 11 - Albuterol (trade names Proventil and Ventolin) is...Ch. 11 - Prob. 11.51PCh. 11 - Prob. 11.52PCh. 11 - Prob. 11.53PCh. 11 - Prob. 11.54PCh. 11 - Prob. 11.55PCh. 11 - GHB is an addictive, illegal recreational drug...Ch. 11 - Prob. 11.57PCh. 11 - Prob. 11.58PCh. 11 - Prob. 11.59PCh. 11 - Prob. 11.60PCh. 11 - Prob. 11.61PCh. 11 - Prob. 11.62PCh. 11 - You are given two unlabeled bottles of solids, one...Ch. 11 - State how potassium iodide (KI) and pentane...Ch. 11 - The given beaker contains 100 mL of the organic...Ch. 11 - Prob. 11.66PCh. 11 - Why do we need to know the shape of a molecule...Ch. 11 - 1,1-Dichloroethylene (CH2=CCl2) is a starting...Ch. 11 - Indicate the polar bonds in each molecule. Label...Ch. 11 - Indicate the polar bonds in each molecule. Label...Ch. 11 - Classify each molecule as polar or nonpolar.Ch. 11 - Classify each molecule as polar or nonpolar. a....Ch. 11 - Which molecule is more water soluble? Explain.Ch. 11 - Explain why pantothenic acid, vitamin B5, is water...Ch. 11 - Prob. 11.75PCh. 11 - Prob. 11.76PCh. 11 - Explain why regularly taking a large excess of a...Ch. 11 - You can obtain the minimum daily requirement of...Ch. 11 - Prob. 11.79PCh. 11 - Vitamin B6 is obtained by eating a diet that...Ch. 11 - Prob. 11.81PCh. 11 - Can an oxygen-containing organic compound, have...Ch. 11 - Prob. 11.83PCh. 11 - Prob. 11.84PCh. 11 - Benzocaine is the active ingredient in topical...Ch. 11 - Methyl salicylate is responsible for the...Ch. 11 - Answer the following questions about aldosterone,...Ch. 11 - Answer the following questions about...Ch. 11 - Prob. 11.89PCh. 11 - Skin moisturizers come in two types, (a) One type...Ch. 11 - THC is the active component in marijuana (Section...Ch. 11 - Cocaine is a widely abused, addicting drug....
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Classify each pair of molecules according to whether or not they can participate in hydrogen bonding with one another. Participate in hydrogen bonding CH3COCH3 and CH3COCH2CH3 H2O and (CH3CH2)2CO CH3COCH3 and CH₂ CHO Answer Bank Do not participate in hydrogen bonding CH3CH2OH and HCHO CH3COCH2CH3 and CH3OHarrow_forwardNonearrow_forwardQ4: Comparing (3S,4S)-3,4-dimethylhexane and (3R,4S)-3,4-dimethylhexane, which one is optically active? Briefly explain.arrow_forward
- Nonearrow_forwardNonearrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 4A (g) + 2B (g) → 2C (g) + 7D (g) AHrxn =?kJ Substance AH in kJ/mol A (g) - 20.42 B (g) + 32.18 C (g) - 72.51 D (g) - 17.87arrow_forward
- Determine ASran for Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(aq) given the following information: Standard Entropy Values of Various Substance Substance So (J/mol • K) 60.9 Zn(s) HCl(aq) 56.5 130.58 H2(g) Zn2+(aq) -106.5 55.10 CI (aq)arrow_forward3) Catalytic hydrogenation of the compound below produced the expected product. However, a byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?arrow_forwardWhat is the ΔHorxn of the reaction? NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq) ΔHorxn 1= ________ kJ/molarrow_forward
- = +92kJ ΔΗ = +170kJ Use the following reactions: 2NH3(9) N2(g) + 3H2(g) → 11/N2(g) + 2H2O (1) → NO2(g) + 2H2(g) Determine the DH° of this reaction: NO2(g) + H2(g) → 2(g) → 2H2O(l) + NH3(9) ΔΗarrow_forwardDetermine the entropy change for the reaction SO2(g) + O2(g) following information: Standard Entropy Values of Various Substance Substance SO2(g) 02(g) SO3(g) So (J/mol K) 248.2 205.0 256.8 → SO3(g) given thearrow_forwardIndicate which one of the following reactions most certainly results in a negative AS sys. O1402(g) + 3NH4NO3 (s) + C10 H22(1) → 3N2(g) + 17H2O(g) + 10CO2(g) ○ CO2(aq) = CO2(g) ○ H₂O(g) = H₂O(s) CaCO3(g) = CaO(s) + CO2(g) O CuSO4.5H2O(s) = CuSO4(s) + 5H2O(g)arrow_forward
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