(a) Interpretation: The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated. Concept introduction: The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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Answer 1

Question

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)

Answer 2

Question

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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Answer 3

Question

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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Answer 4

Question

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

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Answer 5

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 6

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 7

Chapter 11, Problem 11.7P

Interpretation Introduction

(a)

Interpretation:

The synthesis of dicyclohexyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The synthesis of tert-butyl-isobutyl ether using alkoxymercuration-reduction is to be stated.

Concept introduction:

The ethers are synthesized by the reaction of alkene with alcohol in presence of mercuric acetate. In the alkoxy mercuration reduction reaction, the alcohol acts as a nucleophile and reacts with mercurium ion intermediate.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains the synthesis of dicyclohexyl ether using alkoxymercuration-reduction.

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Chapter 11 Solutions